Methanamine, hydrochloride

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
solid,1 bar138.53J/mol*KN/AAston and Ziemer, 1946Using metastable c,II below 220 K gives S = 138.70 J/mol*K.

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
90.92298.15Aston and Ziemer, 1946T = 12 to 298 K.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
114.5533.AStephenson and Malanowski, 1987Based on data from 518. to 593. K.; AC

Enthalpy of phase transition

ΔHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
1.778220.4crystaline, IIIcrystaline, IIAston and Ziemer, 1946DH
2.820264.5crystaline, IIcrystaline, IAston and Ziemer, 1946DH

Entropy of phase transition

ΔStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
8.07220.4crystaline, IIIcrystaline, IIAston and Ziemer, 1946DH
10.66264.5crystaline, IIcrystaline, IAston and Ziemer, 1946DH

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Condensed Phase Spectrum

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IR spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

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Owner Copyright (C) 1987 by the Coblentz Society
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin BRITISH PETROLEUM CO. LTD., ENGLAND
Source reference COBLENTZ NO. 9312
Date 1972/05/09
Name(s) methanamine hydrochloride
Methylamine, hydrochloride
State SOLID (KBr DISC)
HCl RUN IN KBr MAY CONTAIN SOME HBr
REF. Can. J. Spec., 18,4,101, '73 C. S. DOUSE and P. B. TOOKE
Instrument PERKIN-ELMER 157
Resolution 2
Sampling procedure TRANSMISSION
Data processing DIGITIZED BY COBLENTZ SOCIETY (BATCH II) FROM HARD COPY

This IR spectrum is from the Coblentz Society's evaluated infrared reference spectra collection.


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aston and Ziemer, 1946
Aston, J.G.; Ziemer, C.W., Thermodynamic properties of the three crystalline forms of methylammonium chloride, J. Am. Chem. Soc., 1946, 68, 1405-1413. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

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