Digermane, hexaethyl-


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-313.7 ± 9.7kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfliquid-376.5 ± 9.5kJ/molReviewMartinho Simões 
Quantity Value Units Method Reference Comment
Δcliquid-9711.1 ± 8.4kJ/molCC-SBRabinovich, Tel'noi, et al., 1963Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δvap62.8 ± 2.1kJ/molCC-SBRabinovich, Tel'noi, et al., 1963 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
7.48 ± 0.01EIMochida, Worley, et al., 1985LBLHLM
7.48 ± 0.01EIPitt, Bursey, et al., 1970RDSH
7.4 ± 0.2EIdeRidder and Dijkstra, 1968RDSH
8.33PEMochida, Worley, et al., 1985Vertical value; LBLHLM

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C4H13Ge2+14.9 ± 0.2?EIdeRidder and Dijkstra, 1968RDSH
C6H15Ge+10.9 ± 0.2?EIdeRidder and Dijkstra, 1968RDSH
C6H17Ge2+12.9 ± 0.2?EIdeRidder and Dijkstra, 1968RDSH
C8H21Ge2+11.7 ± 0.2?EIdeRidder and Dijkstra, 1968RDSH
C10H25Ge2+9.6 ± 0.2?EIdeRidder and Dijkstra, 1968RDSH

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

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NIST MS number 15173

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Rabinovich, Tel'noi, et al., 1963
Rabinovich, I.B.; Tel'noi, V.I.; Karyakin, N.V.; Razuvaev, G.A., Dokl. Akad. Nauk SSSR, 1963, 149, 324. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Mochida, Worley, et al., 1985
Mochida, K.; Worley, S.; Kochi, J., UV photoelectron spectra of peralkylated catenates of Group 4B elements (silicon, germanium, and tin), Bull. Chem. Soc. Jpn., 1985, 58, 3389. [all data]

Pitt, Bursey, et al., 1970
Pitt, C.G.; Bursey, M.M.; Rogerson, P.F., Catenates of the group IV elements. Correlation of σ electron energies, J. Am. Chem. Soc., 1970, 92, 519. [all data]

deRidder and Dijkstra, 1968
deRidder, J.J.; Dijkstra, G., On the mass spectra of some alkyl digermanium compounds, Org. Mass Spectrom., 1968, 1, 647. [all data]


Notes

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