L-Sorbose

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-1276.9 ± 1.0kJ/molCcbGerasimov, Blokh, et al., 1985ALS
Δfsolid-1271.5 ± 0.50kJ/molCcbClarke and Stegeman, 1939Reanalyzed by Cox and Pilcher, 1970, Original value = -1271.1 kJ/mol; ALS
Quantity Value Units Method Reference Comment
Δcsolid-2799.1 ± 1.0kJ/molCcbGerasimov, Blokh, et al., 1985Corresponding Δfsolid = -1276.9 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-2804.5 ± 0.4kJ/molCcbClarke and Stegeman, 1939Corresponding Δfsolid = -1271.5 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar220.9J/mol*KN/AJack and Stegeman, 1941crystaline, I phase; Extrapolation below 90 K, 50.21 J/mol*K.; DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
228.61295.9Jack and Stegeman, 1941crystaline, I phase; T = 64 to 296 K. Value is unsmoothed experimental datum.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gerasimov, Blokh, et al., 1985
Gerasimov, P.A.; Blokh, E.L.; Gubareva, A.I., Standard heats of formation of intermediates in the synthesis of vitamin C, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1985, 28, 54-56. [all data]

Clarke and Stegeman, 1939
Clarke, T.H.; Stegeman, G., Heats of combustion of some mono- and disaccharides, J. Am. Chem. Soc., 1939, 61, 1726-1730. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Jack and Stegeman, 1941
Jack, G.W.; Stegeman, G., The heat capacities and entropies of two monosaccharides, J. Am. Chem. Soc., 1941, 63, 2121-2123. [all data]


Notes

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