Phenanthrene

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Enthalpy of combustion of solid at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Δcsolid (kJ/mol) Method Reference Comment
-7048.1 ± 1.5CcbSteele, Chirico, et al., 1990Δ Hfusion = 15.96±0.05 kJ/mol; Corresponding Δfsolid = 109.76 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-7054.5 ± 1.3CcbColeman and Pilcher, 1966Author was aware that data differs from previously reported values; Corresponding Δfsolid = 116.2 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-7051.3CcbBender and Farber, 1952Corresponding Δfsolid = 113. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-7049.5 ± 1.4CcbMagnus, Hartmann, et al., 1951Corresponding Δfsolid = 111.3 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-7011.1 ± 2.6CcbRichardson and Parks, 1939High level of uncertainty in the data; Reanalyzed by Cox and Pilcher, 1970, Original value = -7007.99 kJ/mol; see Richardson, 1939; Corresponding Δfsolid = 72.84 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-7050.9 ± 2.7CcbFries, Walter, et al., 1935Reanalyzed by Cox and Pilcher, 1970, Original value = -7046.7 kJ/mol; Corresponding Δfsolid = 112.6 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-7014.31CcbMilone and Rossignoli, 1932Corresponding Δfsolid = 76.02 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

References

Go To: Top, Enthalpy of combustion of solid at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Steele, Chirico, et al., 1990
Steele, W.V.; Chirico, R.D.; Nguyen, A.; Hossenlopp, I.A.; Smith, N.K., Determination of ideal-gas enthalpies of formation for key compounds, Am. Inst. Chem. Eng. Symp. Ser. (AIChE Symp. Ser.), 1990, 138-154. [all data]

Coleman and Pilcher, 1966
Coleman, D.J.; Pilcher, G., Heats of combustion of biphenyl, bibenzyl, naphthalene, anthracene, and phenanthrene, Trans. Faraday Soc., 1966, 62, 821-827. [all data]

Bender and Farber, 1952
Bender, P.; Farber, J., The heats of combustion of anthracene transannular peroxide and dianthracene, J. Am. Chem. Soc., 1952, 74, 1450-1452. [all data]

Magnus, Hartmann, et al., 1951
Magnus, A.; Hartmann, H.; Becker, F., Verbrennungswarmen und resonanzenergien von mehrkernigen aromatischen kohlenwasserstoffen, Z. Phys. Chem., 1951, 197, 75-91. [all data]

Richardson and Parks, 1939
Richardson, J.W.; Parks, G.S., Thermal data on organic compounds. XIX. Modern combustion data for some non-volatile compounds containing carbon, hydrogen and oxygen, J. Am. Chem. Soc., 1939, 61, 3543-3546. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Richardson, 1939
Richardson, J.W., Precise determination of the heats of combustion of some representative organic compounds, Ph.D. Thesis for Standford University, 1939, 1-122. [all data]

Fries, Walter, et al., 1935
Fries, K.; Walter, R.; Schilling, K., Uber tricyclische verbindungen in denen naphtalin mit einem heterocyclus anelliert ist, Ann. Chim., 1935, 516, 248-285. [all data]

Milone and Rossignoli, 1932
Milone, M.; Rossignoli, P., Sul calore di combustione di alcune miscele di composti organici, Gazz. Chim. Ital., 1932, 62, 644-655. [all data]


Notes

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