Methyl 2-methyl-3-methoxy-3-butenoate

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

Methyl 2-methyl-3-methoxy-3-butenoate = (E) Methyl-3-methoxy-2-methyl-2-butenoate

By formula: C7H12O3 = C7H12O2

Quantity Value Units Method Reference Comment
Δr-9.1 ± 0.7kJ/molEqkTaskinen and Mukkala, 1982liquid phase; solvent: Cyclohexane

Methyl 2-methyl-3-methoxy-3-butenoate = 2-Butenoic acid, 3-methoxy-2-methyl-, methyl ester, (Z)-

By formula: C7H12O3 = C7H12O3

Quantity Value Units Method Reference Comment
Δr-1.9 ± 1.1kJ/molEqkTaskinen and Mukkala, 1982liquid phase; solvent: Cyclohexane

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Taskinen and Mukkala, 1982
Taskinen, E.; Mukkala, V-M, Thermodynamics of vinyl ethers-XXVII. Thermodynamic stability of β-methoxy-substituted α,β-unsaturated ketones and the corresponding carboxylic esters, Tetrahedron, 1982, 38, 613-616. [all data]


Notes

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