Hydrogen sulfide

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CH6N+ + Hydrogen sulfide = (CH6N+ • Hydrogen sulfide)

By formula: CH6N+ + H2S = (CH6N+ • H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr45.2kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.270.PHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

CN- + Hydrogen sulfide = (CN- • Hydrogen sulfide)

By formula: CN- + H2S = (CN- • H2S)

Quantity Value Units Method Reference Comment
Δr79.1 ± 4.2kJ/molTDEqMeot-ner, 1988gas phase; B
Δr83. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr99.6J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Δr54.0 ± 4.2kJ/molTDEqMeot-ner, 1988gas phase; B
Δr51.9 ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

C3H7+ + Hydrogen sulfide = (C3H7+ • Hydrogen sulfide)

By formula: C3H7+ + H2S = (C3H7+ • H2S)

Quantity Value Units Method Reference Comment
Δr134.kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; condensation; M
Quantity Value Units Method Reference Comment
Δr146.J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; condensation; M

Fluorine anion + Hydrogen sulfide = (Fluorine anion • Hydrogen sulfide)

By formula: F- + H2S = (F- • H2S)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr145. ± 8.4kJ/molIMRELarson and McMahon, 1983gas phase; These relative affinities are ca. 10 kcal/mol weaker than threshold values (see Wenthold and Squires, 1995) for donors greater than ca. 27 kcal/mol in free energy. This discrepancy has not yet been resolved, though the stronger value appears preferable.; B,M
Quantity Value Units Method Reference Comment
Δr78.7J/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
Δr121. ± 8.4kJ/molIMRELarson and McMahon, 1983gas phase; These relative affinities are ca. 10 kcal/mol weaker than threshold values (see Wenthold and Squires, 1995) for donors greater than ca. 27 kcal/mol in free energy. This discrepancy has not yet been resolved, though the stronger value appears preferable.; B,M

F5S- + Hydrogen sulfide = (F5S- • Hydrogen sulfide)

By formula: F5S- + H2S = (F5S- • H2S)

Quantity Value Units Method Reference Comment
Δr212. ± 48.kJ/molSIFTZangerle, Hansel, et al., 1993gas phase; CID with Ar; M

HS- + Hydrogen sulfide = (HS- • Hydrogen sulfide)

By formula: HS- + H2S = (HS- • H2S)

Quantity Value Units Method Reference Comment
Δr55.2 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr82.4J/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr31. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B

H2S+ + Hydrogen sulfide = (H2S+ • Hydrogen sulfide)

By formula: H2S+ + H2S = (H2S+ • H2S)

Quantity Value Units Method Reference Comment
Δr88.7kJ/molPIPrest, Tzeng, et al., 1983gas phase; M
Δr71.1kJ/molPIWalters and Blais, 1981gas phase; M

(H2S+ • Hydrogen sulfide) + Hydrogen sulfide = (H2S+ • 2Hydrogen sulfide)

By formula: (H2S+ • H2S) + H2S = (H2S+ • 2H2S)

Quantity Value Units Method Reference Comment
Δr18.kJ/molPIPrest, Tzeng, et al., 1983gas phase; M
Δr13.kJ/molPIWalters and Blais, 1981gas phase; M

(H2S+ • 2Hydrogen sulfide) + Hydrogen sulfide = (H2S+ • 3Hydrogen sulfide)

By formula: (H2S+ • 2H2S) + H2S = (H2S+ • 3H2S)

Quantity Value Units Method Reference Comment
Δr5.0kJ/molPIWalters and Blais, 1981gas phase; M

(H2S+ • 3Hydrogen sulfide) + Hydrogen sulfide = (H2S+ • 4Hydrogen sulfide)

By formula: (H2S+ • 3H2S) + H2S = (H2S+ • 4H2S)

Quantity Value Units Method Reference Comment
Δr5.9kJ/molPIWalters and Blais, 1981gas phase; M

(H2S+ • 4Hydrogen sulfide) + Hydrogen sulfide = (H2S+ • 5Hydrogen sulfide)

By formula: (H2S+ • 4H2S) + H2S = (H2S+ • 5H2S)

Quantity Value Units Method Reference Comment
Δr11.kJ/molPIWalters and Blais, 1981gas phase; M

H3S+ + Hydrogen sulfide = (H3S+ • Hydrogen sulfide)

By formula: H3S+ + H2S = (H3S+ • H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr64.4kJ/molPHPMSHiraoka and Kebarle, 1977gas phase; M
Δr45.2kJ/molPIWalters and Blais, 1984gas phase; M
Δr44.4kJ/molPIPrest, Tzeng, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr102.J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase; M
Δr74.5J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; Entropy change is questionable; M
Δr78.2J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; M

(H3S+ • Hydrogen sulfide) + Hydrogen sulfide = (H3S+ • 2Hydrogen sulfide)

By formula: (H3S+ • H2S) + H2S = (H3S+ • 2H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr38.kJ/molPHPMSHiraoka and Kebarle, 1977gas phase; M
Δr25.kJ/molPIWalters and Blais, 1984gas phase; M
Δr30.kJ/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; M
Quantity Value Units Method Reference Comment
Δr87.4J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase; M
Δr72.4J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; M

(H3S+ • 2Hydrogen sulfide) + Hydrogen sulfide = (H3S+ • 3Hydrogen sulfide)

By formula: (H3S+ • 2H2S) + H2S = (H3S+ • 3H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr18.kJ/molPIWalters and Blais, 1984gas phase; M
Δr35.kJ/molPHPMSHiraoka and Kebarle, 1977gas phase; M
Δr23.kJ/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr103.J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase; M
Δr59.J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; Entropy change is questionable; M

(H3S+ • 3Hydrogen sulfide) + Hydrogen sulfide = (H3S+ • 4Hydrogen sulfide)

By formula: (H3S+ • 3H2S) + H2S = (H3S+ • 4H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr28.kJ/molPHPMSHiraoka and Kebarle, 1977gas phase; M
Δr10.kJ/molPIWalters and Blais, 1984gas phase; M
Δr14.kJ/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr103.J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase; M
Δr42.J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; Entropy change is questionable; M

(H3S+ • 4Hydrogen sulfide) + Hydrogen sulfide = (H3S+ • 5Hydrogen sulfide)

By formula: (H3S+ • 4H2S) + H2S = (H3S+ • 5H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr26.kJ/molPHPMSHiraoka and Kebarle, 1977gas phase; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
7.1185.PHPMSHiraoka and Kebarle, 1977gas phase; M

NH4+ + Hydrogen sulfide = (NH4+ • Hydrogen sulfide)

By formula: H4N+ + H2S = (H4N+ • H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr47.7kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr69.9J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

Iodide + Hydrogen sulfide = (Iodide • Hydrogen sulfide)

By formula: I- + H2S = (I- • H2S)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr37. ± 4.2kJ/molTDAsCaldwell, Masucci, et al., 1989gas phase; B,M

Nitric oxide anion + Hydrogen sulfide = H2NOS-

By formula: NO- + H2S = H2NOS-

Quantity Value Units Method Reference Comment
Δr23.4kJ/molN/AHendricks, de Clercq, et al., 2002gas phase; B

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner) and Sieck, 1985
Meot-Ner (Mautner), M.; Sieck, L.W., The Ionic Hydrogen Bond and Ion Solvation. 4. SH+ O and NH+ S Bonds. Correlations with Proton Affinity. Mutual Effects of Weak and Strong Ligands in Mixed Clusters, J. Phys. Chem., 1985, 89, 24, 5222, https://doi.org/10.1021/j100270a021 . [all data]

Meot-ner, 1988
Meot-ner, M., Ionic Hydrogen Bond and Ion Solvation. 6. Interaction Energies of the Acetate Ion with Organic Molecules. Comparison of CH3COO- with Cl-, CN-, and SH-, J. Am. Chem. Soc., 1988, 110, 12, 3854, https://doi.org/10.1021/ja00220a022 . [all data]

Larson and McMahon, 1987
Larson, J.W.; McMahon, T.B., Hydrogen bonding in gas phase anions. The energetics of interaction between cyanide ion and bronsted acids, J. Am. Chem. Soc., 1987, 109, 6230. [all data]

Payzant, Yamdagni, et al., 1971
Payzant, J.D.; Yamdagni, R.; Kebarle, P., Hydration of CN-, NO2-, NO3-, and HO- in the gas phase, Can. J. Chem., 1971, 49, 3308. [all data]

Meot-Ner (Mautner) and Sieck, 1991
Meot-Ner (Mautner), M.; Sieck, L.W., Proton affinity ladders from variable-temperature equilibrium measurements. 1. A reevaluation of the upper proton affinity range, J. Am. Chem. Soc., 1991, 113, 12, 4448, https://doi.org/10.1021/ja00012a012 . [all data]

Larson and McMahon, 1983
Larson, J.W.; McMahon, T.B., Strong hydrogen bonding in gas-phase anions. An ion cyclotron resonance determination of fluoride binding energetics to bronsted acids from gas-phase fluoride exchange equilibria measurements, J. Am. Chem. Soc., 1983, 105, 2944. [all data]

Wenthold and Squires, 1995
Wenthold, P.G.; Squires, R.R., Bond dissociation energies of F2(-) and HF2(-). A gas-phase experimental and G2 theoretical study, J. Phys. Chem., 1995, 99, 7, 2002, https://doi.org/10.1021/j100007a034 . [all data]

Arshadi, Yamdagni, et al., 1970
Arshadi, M.; Yamdagni, R.; Kebarle, P., Hydration of Halide Negative Ions in the Gas Phase. II. Comparison of Hydration Energies for the Alkali Positive and Halide Negative Ions, J. Phys. Chem., 1970, 74, 7, 1475, https://doi.org/10.1021/j100702a014 . [all data]

Zangerle, Hansel, et al., 1993
Zangerle, R.; Hansel, A.; Richter, R.; Lindinger, W., The Reaction of SF5+ + H2S at Near Thermal Energies: Competition between Association and Binary Reactions, Int. J. Mass Spectrom. Ion Proc., 1993, 129, 117, https://doi.org/10.1016/0168-1176(93)87035-Q . [all data]

Prest, Tzeng, et al., 1983
Prest, H.F.; Tzeng, W.-B.; Brom, J.M., Jr.; Ng, C.Y., Photoionization study of (H2S)2 and (H2S)3, J. Am. Chem. Soc., 1983, 105, 7531. [all data]

Walters and Blais, 1981
Walters, E.A.; Blais, N.C., Molecular beam photoionization of (H2S)n,n = 1 - 7, J. Chem. Phys., 1981, 75, 4208. [all data]

Hiraoka and Kebarle, 1977
Hiraoka, K.; Kebarle, P., Gas Phase Ion Equilibria Studies of the Proton in Hydrogen Sulfide and Hydrogen Sulfide - Water Mixtures. Stabilities of the Hydrogen Bonded Complexes H+(H2S)x(H2O)y, Can. J. Chem., 1977, 55, 1, 24, https://doi.org/10.1139/v77-005 . [all data]

Walters and Blais, 1984
Walters, E.A.; Blais, N.C., Molecular beam photoionization and fragmentation of D2S, (H2S)2, (D2S)2, and H2S.H2O, J. Chem. Phys., 1984, 80, 3501. [all data]

Meot-Ner (Mautner) and Field, 1977
Meot-Ner (Mautner), M.; Field, F.H., Stability, Association and Dissociation in the Cluster Ions H3S+.nH2S, H3O+.nH2O and H3O+.H2O, J. Am. Chem. Soc., 1977, 99, 4, 998, https://doi.org/10.1021/ja00446a004 . [all data]

Caldwell, Masucci, et al., 1989
Caldwell, G.W.; Masucci, J.A.; Ikonomou, M.G., Negative Ion Chemical Ionization Mass Spectrometry - Binding of Molecules to Bromide and Iodide Anions, Org. Mass Spectrom., 1989, 24, 1, 8, https://doi.org/10.1002/oms.1210240103 . [all data]

Hendricks, de Clercq, et al., 2002
Hendricks, J.H.; de Clercq, H.L.; Freidhoff, C.B.; Arnold, S.T.; Eaton, J.G.; Fancher, C.; Lyapustina, S.A.; S., Anion solvation at the microscopic level: Photoelectron spectroscopy of the solvated anion clusters, NO-(Y)(n), where Y=Ar, Kr, Xe, N2O, H2S, NH3, H2O, and C2H4(OH)(2), J. Chem. Phys., 2002, 116, 18, 7926-7938, https://doi.org/10.1063/1.1457444 . [all data]


Notes

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