2-Propanol, 2-methyl-

• Formula: C₄H₁₀O
• Molecular weight: 74.1216
• IUPAC Standard InChI: InChI=1S/C4H10O/c1-4(2,3)5/h5H,1-3H3 Copy

  
• IUPAC Standard InChIKey: DKGAVHZHDRPRBM-UHFFFAOYSA-N Copy
• CAS Registry Number: 75-65-0
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Isotopologues:
  • 2-Propanol, 2-methyl-d
  • 2-Propanol, 2-methyl-d
• Other names: tert-Butyl alcohol; tert-Butanol; Ethanol, 1,1-Dimethyl-; Trimethylcarbinol; Trimethylmethanol; 1,1-Dimethylethanol; 2-Methyl-2-propanol; tert-C4H9OH; t-Butanol; tert-Butyl hydroxide; 2-Methylpropanol-2; 2-Methylpropan-2-ol; Alcool butylique tertiaire; Butanol tertiaire; t-Butyl hydroxide; Methanol, trimethyl-; NCI-C55367; 2-Methyl n-propan-2-ol; Methyl-2 propanol-2; Tert.-butyl alcohol
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Normal boiling point
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Phase change data
  • Reaction thermochemistry data
  • Henry's Law data
  • Gas phase ion energetics data
  • Ion clustering data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • Gas Chromatography
• Data at other public NIST sites:
  • Computational Chemistry Comparison and Benchmark Database
  • Gas Phase Kinetics Database
• Options:
  • Switch to SI units

Data at NIST subscription sites:

• NIST / TRC Web Thermo Tables, "lite" edition (thermophysical and thermochemical data)
• NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data)

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.

Normal boiling point

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
BS - Robert L. Brown and Stephen E. Stein

References

Go To: Top, Normal boiling point, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Loras, Aucejo, et al., 1999
Loras, S.; Aucejo, A.; Munoz, R.; Ordonez, L.M., Phase Equilibria in the Systems 2-Methyl-2-propanol + Methyl 1,1-Dimethylpropyl Ether and 2-Methylpentane + 2-Methyl-2-propanol + Methyl 1,1-Dimethylpropyl Ether, J. Chem. Eng. Data, 1999, 44, 1163-8. [all data]

Loras, Aucejo, et al., 1999, 2
Loras, S.; Aucejo, A.; Munoz, R., Isobsaric Vapor-Liquid equilibrium in the Systems Methyl 1,1-Dimethylethyl Ether + 2-Methyl-2-propanol and Methyl 1,1-Dimethylethyl Ether + 2-Methylpentane + 2-Methyhl-2-propanol, J. Chem. Eng. Data, 1999, 44, 1169-74. [all data]

Reddy, Rambabu, et al., 1995
Reddy, V.K.; Rambabu, K.; Devarajulu, T.; Krishnaiah, A., Volume of Mixing, Speed of Sound, and Viscosity of Methyl Cellosolve with Aliphatic Alcohols at 308.15 K, J. Chem. Eng. Data, 1995, 40, 124-7. [all data]

Reddy and Rao, 1989
Reddy, B.S.; Rao, B.V.S., Vapor-liquid equilibrium data of tert-butyl alcohol-chlorobenzene at 101.3 kPa, J. Chem. Eng. Data, 1989, 34, 26. [all data]

Reddy and Subbarao, 1989
Reddy, B.S.; Subbarao, B.V., Vapor-Liquid Equilibrium Data of tert-Butyl Alcohol-Chlorobenzene at 101.3 kPa, J. Chem. Eng. Data, 1989, 34, 26. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

American Tokyo Kasei, 1988
American Tokyo Kasei, TCI American Organic Chemical 88/89 Catalog, American Tokyo Kasei, Portland, OR, 1988, 1610. [all data]

Aquirre-Ode and Koo, 1988
Aquirre-Ode, F.; Koo, J., Activity Coefficients in Thiophene-Butanol Systems Near the Freezing Point of Thiophene, J. Chem. Eng. Data, 1988, 33, 310. [all data]

Wisniak and Tamir, 1988
Wisniak, J.; Tamir, A., Vapor-Liquid Equilibria at 760 mmHg in the Systems Propyl Bromide- tert-Butyl Alcohol and Propyl Bromide-p-Xylene, J. Chem. Eng. Data, 1988, 33, 106. [all data]

Krishnaiah and Choudary, 1987
Krishnaiah, A.; Choudary, N.V., Activity Coefficients and Excess Gibbs Free Energies of 1,2-Dichlor- ethane with Isomeric Butanols, J. Chem. Eng. Data, 1987, 32, 196. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Rao and Reddy, 1985
Rao, K.P.C.; Reddy, K.S. (see subram k), Excess volumes and excess isentropic compressibilities of binary mixtures of N. N. dimethylformamide with branched alcohols at 303.15K, Thermochim. Acta, 1985, 91, 321. [all data]

Tamir and Wisniak, 1978
Tamir, A.; Wisniak, J., Vapor-liquid equilibria in the ternary systems tert-butyl alcohol + diethyl ketone + methyl isobutyl ketone and diethyl ketone + methyl isobutyl ketone + n-butyl alcohol and their binaries, J. Chem. Eng. Data, 1978, 23, 293-8. [all data]

Govindaswamy, Andiappan, et al., 1977
Govindaswamy, S.; Andiappan, A.N.; Lakshmanan, S.M., Vapor-liquid equilibria of the binary and ternary systems containing n- hexane(1) + benzene(2) + tert-butyl alcohol(3) at 760 mm hg pressure, J. Chem. Eng. Data, 1977, 22, 264. [all data]

Tripathi, Krishna, et al., 1976
Tripathi, R.P.; Krishna, S.; Gulati, I.B., Isobaric Binary Vapor-Liquid Equilibria in Cyclohexane-tert-Butyl Alcohol and 2,4-Dimethylpenbtane-tert-Butyl Alcohol Systems, J. Chem. Eng. Data, 1976, 21, 44. [all data]

Wisniak and Tamir, 1975
Wisniak, J.; Tamir, A., Vapor-liquid equilibria of sec-butanol + isobutanol, sec-butanol + tert- butanol, and isobutanol + tert-butanol systems, J. Chem. Eng. Data, 1975, 20, 388. [all data]

Wisniak and Tamir, 1975, 2
Wisniak, J.; Tamir, A., Ternary vapor-liquid equilibria for system n-butanol + sec-butanol + tert- butanol, J. Chem. Eng. Data, 1975, 20, 393. [all data]

Lesteva and Timofeev, 1972
Lesteva, T.M.; Timofeev, G.A., Phase equilibria in methanol + 4,4-dimethyl-1,3-dioxane and trimethyl carbinol + 4,4-dimethyl-1,3-dioxane systems, Zh. Prikl. Khim. (Leningrad), 1972, 45, 695-697. [all data]

Suska, Holub, et al., 1970
Suska, J.; Holub, R.; Vonka, P.; Pick, J., Liquid-Vapor Equilibrium XLII. Systems: Ethyl Alcohol-Water-tert- Butyl Alcohol and Ethyl Alcohol-Water-Isobutyl Alcohol, Collect. Czech. Chem. Commun., 1970, 35, 385-95. [all data]

Brown, Fock, et al., 1969
Brown, I.; Fock, W.; Smith, F., The thermodynamic properties of solutions of normal and branched alcohols in benzene and n-hexane., J. Chem. Thermodyn., 1969, 1, 273. [all data]

Brown and Smith, 1962
Brown, I.; Smith, F., Aust. J. Chem., 1962, 15, 3-8. [all data]

Barnard, 1959
Barnard, J.A., Trans. Faraday Soc., 1959, 55, 947. [all data]

Mikus and Lawler, 1958
Mikus, F.F.; Lawler, C.W., Liquid-vapor equilibria for the system nitrobenzene + t-butyl alcohol, J. Phys. Chem., 1958, 62, 880. [all data]

Morton, Cala, et al., 1956
Morton, M.; Cala, J.A.; Piirma, I., The Branching Reaction I. Chain Transfer of Styrene with Thiol, Alcohol, and Nitrile, J. Am. Chem. Soc., 1956, 78, 5394-8. [all data]

Omura, Higasi, et al., 1956
Omura, I.; Higasi, K.; Baba, H., Ionization potentials of some organic molecules. II. Aliphatic compounds, Bull. Chem. Soc. Japan, 1956, 29, 504. [all data]

Rathmann, Curtis, et al., 1956
Rathmann, G.B.; Curtis, A.J.; McGeer, P.L.; Smyth, C.P., Microwave Absorption and Molecular Structure in Liquids. XIV. The Apparent Critical Wave Lengths of Liquid Long Chain Alcohols, J. Am. Chem. Soc., 1956, 78, 2035-8. [all data]

Stutchbury, 1956
Stutchbury, J.E., Compressions of Organic Liquids and Their Mixtures with Water, Aust. J. Chem., 1956, 9, 536-540. [all data]

Bassey, Bunton, et al., 1955
Bassey, M.; Bunton, C.A.; Davis, A.G.; Lewis, T.A.; Llewellen, D.R., J. Chem. Soc., 1955, 1955, 2471. [all data]

Criegee, Kerckow, et al., 1955
Criegee, R.; Kerckow, A.; Zinke, H., Chem. Ber., 1955, 88, 1878. [all data]

McElvain and McKay, 1955
McElvain, S.M.; McKay, G.R., J. Am. Chem. Soc., 1955, 77, 5601. [all data]

Walling and Buckler, 1955
Walling, C.; Buckler, S.A., J. Am. Chem. Soc., 1955, 77, 6032. [all data]

Westwater, 1955
Westwater, J.H., Liquid-phase equilibria in system water + tert-butyl alcohol + tert-butyl hypochlorite effect of temperature, Ind. Eng. Chem., 1955, 47, 451. [all data]

Urry, Stacey, et al., 1954
Urry, W.H.; Stacey, F.W.; Huyser, E.S.; Juveland, O.O., The Peroxide- and Light-induced Additions of Alcohols to Olefins, J. Am. Chem. Soc., 1954, 76, 450. [all data]

Westwater and Audrieth, 1954
Westwater, J.W.; Audrieth, L.F., Liquid phase equilibria system tert-butyl alcohol + tert-butyl hypochlorite + water, Ind. Eng. Chem., 1954, 46, 1281. [all data]

McKenna, Tartar, et al., 1953
McKenna, F.E.; Tartar, H.V.; Lingafelter, E.C., Studies of hemiacetal formation in alcohol - aldehyde systems: II refraction studies, J. Am. Chem. Soc., 1953, 75, 604-7. [all data]

West, Senise, et al., 1952
West, P.W.; Senise, P.; Burkhalter, T.S., Anal. Chem., 1952, 24, 1250. [all data]

Pino, Ercoli, et al., 1951
Pino, P.; Ercoli, R.; Mantica, E., Gazz. Chim. Ital., 1951, 81, 635. [all data]

Campbell, Burney, et al., 1950
Campbell, T.W.; Burney, W.; Jacobs, T.L., THe Reaction of Gignard Reagents with D-t-butyl Peroxide, J. Am. Chem. Soc., 1950, 72, 2735. [all data]

Pichler, Ziesecke, et al., 1950
Pichler, H.; Ziesecke, K.H.; Traeger, B., The Oxygen-containing Compounds, Especially Alcohols, Formed in Isosynthesis, Brennst.-Chem., 1950, 31, 361. [all data]

Dreisbach and Martin, 1949
Dreisbach, R.R.; Martin, R.A., Physical Data on Some Organic Compounds, Ind. Eng. Chem., 1949, 41, 2875-8. [all data]

Lecat, 1949
Lecat, M., Tables Azeotropiques, Vol. 1, 10th ed., Brussels, Belgium, 1949. [all data]

Lecat, 1947
Lecat, M., Orthobaric Azeotropes of Sulfides, Bull. Cl. Sci., Acad. R. Belg., 1947, 33, 160-82. [all data]

Lecat, 1947, 2
Lecat, M., Some azeotropes of which one constituant is heterocyclic nitrogen, Ann. Soc. Sci. Bruxelles, Ser. 1, 1947, 61, 73. [all data]

Lecat, 1946
Lecat, M., Binary orthobaric azeotropes containing an alkyl halide, C. R. Hebd. Seances Acad. Sci., 1946, 223, 478. [all data]

Pollock, Collett, et al., 1946
Pollock, D.L.; Collett, A.R.; Lazzell, C.L., The solubility of acetyl-p-toluidine in various solvents, J. Phys. Chem., 1946, 50, 23-9. [all data]

Scattergood, Miller, et al., 1945
Scattergood, A.; Miller, W.H.; Gammon, J., Jr., New Aliphatic Borates, J. Am. Chem. Soc., 1945, 67, 2150. [all data]

Platt, Rusoff, et al., 1943
Platt, J.R.; Rusoff, I.I.; Klevens, H.B., J. Chem. Phys., 1943, 11, 535. [all data]

Getman, 1940
Getman, F.H., Timethylcarbinol as a cryoscopic solvent, J. Am. Chem. Soc., 1940, 62, 2179. [all data]

Crooks, 1938
Crooks, H.M., Unpublished, 1938, Univ. Park, PA 1938. [all data]

Getman, 1936
Getman, F.H., Cryoscopic studies of solutions in Formamide., Recl. Trav. Chim. Pays-Bas, 1936, 55, 969. [all data]

Ipatieff, Corson, et al., 1936
Ipatieff, V.N.; Corson, B.B.; Pines, H., Influence of Sulfuric Acid Concentration upon Reaction between Olefins and Benzene, J. Am. Chem. Soc., 1936, 58, 919-22. [all data]

Komarewsky, Johnstone, et al., 1934
Komarewsky, V.I.; Johnstone, W.; Yoder, P., J. Am. Chem. Soc., 1934, 56, 2705. [all data]

Timmermans and Delcourt, 1934
Timmermans, J.; Delcourt, Y., Work of the International Bureau of Physico-Chemical Standards.VI. Physical Constants of Twenty Organic Compounds., J. Chim. Phys. Phys.-Chim. Biol., 1934, 31, 85-121. [all data]

Webb and Lindsley, 1934
Webb, T.J.; Lindsley, C.H., The cryoscopic study of certain aliphatic alcohols, J. Am. Chem. Soc., 1934, 56, 874. [all data]

Smyth and Dornte, 1931
Smyth, C.P.; Dornte, R.W., Electric moment and molecualr structure: II tertiary butyl and triphenylmethyl chlorides and alcohols, J. Am. Chem. Soc., 1931, 53, 545-55. [all data]

Bhatnagar, Mathur, et al., 1930
Bhatnagar, S.S.; Mathur, R.N.; Mal, R.S., Philos. Mag., 1930, 10, 101. [all data]

Lecat, 1930
Lecat, M., Azeotropism in Binary Mixtures Containing an Alcohol Mixed with an amine, a nitro derivative, an ether or water., Z. Anorg. Allg. Chem., 1930, 186, 119. [all data]

Prentiss, 1929
Prentiss, S.W., The reactivity of atoms and groups in organic compounds. IX. the vapor pressures, densities and refractive indices of certain binary mixtures, J. Am. Chem. Soc., 1929, 51, 2825. [all data]

Swarts, 1929
Swarts, F., Triflourated alcohols: triflouroisopropyl alcohol, Bull. Soc. Chim. Belg., 1929, 38, 99-109. [all data]

Adkins and Broderick, 1928
Adkins, H.; Broderick, A.E., Hemiacetal Formation and the Refractive Indices and Densities of Mixtures of Certain Alcohols and Aldehydes, J. Am. Chem. Soc., 1928, 50, 499. [all data]

Parks and Barton, 1928
Parks, G.S.; Barton, B., Vapor pressure data for isopropyl alcohol and tertiary butyl alcohol, J. Am. Chem. Soc., 1928, 50, 24-6. [all data]

Munch, 1926
Munch, J.C., The Refractometric Determination of Alcohols and Esters in Aqueous and in Cottonseed Oil Solutions, J. Am. Chem. Soc., 1926, 48, 994-1003. [all data]

Norris and Ashdown, 1925
Norris, J.F.; Ashdown, A.A., The Reactivity of Atoms and Groups in Org. Comp. I. The Relative Reactivities of the Hydroxyl-Hydrogen Atoms in Certain Alochols, J. Am. Chem. Soc., 1925, 47, 837-46. [all data]

Willcox and Brunel, 1916
Willcox, M.; Brunel, R.F., J. Am. Chem. Soc., 1916, 38, 1821. [all data]

Doroshevskii, 1911
Doroshevskii, A.G., Zh. Russ. Fiz.-Khim. O-va., Chast Khim., 1911, 43, 66. [all data]

Richards and Mathews, 1908
Richards, T.W.; Mathews, J.H., The Relation Between Compressibility, Surface Tension, and Other Properties of Material, J. Am. Chem. Soc., 1908, 30, 8-13. [all data]

Carrara and Ferrari, 1906
Carrara, G.; Ferrari, G., Gazz. Chim. Ital., 1906, 36, 1419. [all data]

Perkin, 1884
Perkin, W.H., On the Magnetic Rotary Polarisation of Compounds in Relation to their Chemical Consitution; with Observations on the Preparation and Relative Densities of the Bodies Examined, J. Chem. Soc., 1884, 45, 421-580. [all data]

Linnemann and von Zotta, 1872
Linnemann, E.; von Zotta, V., Conversion of Normal Butyl Alcohol into Isobutyl Alcohol or Butyl Alcohol of Fermentation, Justus Liebigs Ann. Chem., 1872, 162, 3. [all data]

Notes

Go To: Top, Normal boiling point, References

• Symbols used in this document:
  

  Tboil

  Boiling point

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.