Acetylene

• Formula: C₂H₂
• Molecular weight: 26.0373
• IUPAC Standard InChI: InChI=1S/C2H2/c1-2/h1-2H Copy

  
• IUPAC Standard InChIKey: HSFWRNGVRCDJHI-UHFFFAOYSA-N Copy
• CAS Registry Number: 74-86-2
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Ethyne; Ethine; Narcylen; C2H2; Acetylen; UN 1001; Vinylene
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Phase change data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Reaction thermochemistry data
  • Henry's Law data
  • Gas phase ion energetics data
  • Ion clustering data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • Vibrational and/or electronic energy levels
  • Gas Chromatography
• Data at other public NIST sites:
  • Microwave spectra (on physics lab web site)
  • Electron-Impact Ionization Cross Sections (on physics web site)
  • Computational Chemistry Comparison and Benchmark Database
  • Gas Phase Kinetics Database
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis

Enthalpy of vaporization

Antoine Equation Parameters

log₁₀(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Enthalpy of sublimation

Enthalpy of fusion

Entropy of fusion

References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M., Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]

Maass and Wright, 1921
Maass, O.; Wright, C.H., SOME PHYSICAL PROPERTIES OF HYDROCARBONS CONTAINING TWO AND THREE CARBON ATOMS., J. Am. Chem. Soc., 1921, 43, 5, 1098-1111, https://doi.org/10.1021/ja01438a013 . [all data]

Morehouse and Maass, 1931
Morehouse, F.R.; Maass, O., The Preparationa and Physical Properties of Ethyl and Methyl Acetylene, Can. J. Res., 1931, 5, 306. [all data]

Maass and Russell, 1918
Maass, O.; Russell, J., Unsaturation and molecular compound formation, J. Am. Chem. Soc., 1918, 40, 1561-1573. [all data]

McIntosh, 1907
McIntosh, D., The physical properties of liquid and solid acetylene., J. Phys. Chem., 1907, 11, 306-17. [all data]

Clark and Din, 1950
Clark, A.M.; Din, F., Equilibria Between Solid, Liquid, and Gaseous Phases at Low Temperature binary systems acetylene - carbon dioxide, acetylene - ethylene and acetylene - ethane, Trans. Faraday Soc., 1950, 46, 901. [all data]

Tsonopoulos and Ambrose, 1996
Tsonopoulos, C.; Ambrose, D., Vapor-Liquid Critical Properties of Elements and Compounds. 6. Unsaturated Aliphatic Hydrocarbons, J. Chem. Eng. Data, 1996, 41, 645-656. [all data]

Goloborod'ko and Khodeeva, 1972
Goloborod'ko, N.P.; Khodeeva, S.M., Russ. J. Phys. Chem. (Engl. Transl.), 1972, 46, 235-7. [all data]

Khodeeva, 1966
Khodeeva, S.M., Visual Observation of Gas-Gas Mixture, Russ. J. Phys. Chem. (Engl. Transl.), 1966, 40, 1061-3. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Reid, 1972
Reid, Robert C., Handbook on vapor pressure and heats of vaporization of hydrocarbons and related compounds, R. C. Wilhort and B. J. Zwolinski, Texas A Research Foundation. College Station, Texas(1971). 329 pages.$10.00, AIChE J., 1972, 18, 6, 1278-1278, https://doi.org/10.1002/aic.690180637 . [all data]

Ambrose and Townsend, 1964
Ambrose, D.; Townsend, R., Vapour pressure of acetylene, Trans. Faraday Soc., 1964, 60, 1025, https://doi.org/10.1039/tf9646001025 . [all data]

Ambrose, 1956
Ambrose, D., The vapour pressures and critical temperatures of acetylene and carbon dioxide, Trans. Faraday Soc., 1956, 52, 772, https://doi.org/10.1039/tf9565200772 . [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Ambrose and Townsend, 1964, 2
Ambrose, D.; Townsend, R., Vapour Pressure of Acetylene, Trans. Faraday Soc., 1964, 60, 1025-1029, https://doi.org/10.1039/tf9646001025 . [all data]

Ambrose, 1956, 2
Ambrose, D., The Vapour Pressures and Critical Temperatures of Acetylene and Carbon Dioxide, Trans. Faraday Soc., 1956, 52, 772-781, https://doi.org/10.1039/tf9565200772 . [all data]

Jones, 1960
Jones, A.H., Sublimation Pressure Data for Organic Compounds., J. Chem. Eng. Data, 1960, 5, 2, 196-200, https://doi.org/10.1021/je60006a019 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Burbo, 1943
Burbo, P.Z., Russ. J. Phys. Chem., 1943, 7, 286. [all data]

Miskiewicz, Rieser, et al., 2010
Miskiewicz, Stefan; Rieser, Klaus; Dorfmüller, Thomas, Thermodynamische Untersuchungen an kondensierten Phasen, Berichte der Bunsengesellschaft für physikalische Chemie, 2010, 80, 5, 395-405, https://doi.org/10.1002/bbpc.19760800504 . [all data]

Miskiewicz, Rieser, et al., 1976
Miskiewicz, S.; Rieser, K.; Dorfmuller, T., Thermodynamische Untersuchungen an kondensierten Phasen, Ber. Bunsen-Ges. Physik. Chem., 1976, 80, 5, 395, https://doi.org/10.1002/bbpc.19760800504 . [all data]

Notes

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• Symbols used in this document:
  

  Pc	Critical pressure
  Ptriple	Triple point pressure
  Tboil	Boiling point
  Tc	Critical temperature
  Tfus	Fusion (melting) point
  Ttriple	Triple point temperature
  Vc	Critical volume
  ΔfusH	Enthalpy of fusion
  ΔfusS	Entropy of fusion
  ΔsubH	Enthalpy of sublimation
  ΔvapH	Enthalpy of vaporization
  ρc	Critical density

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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