rubidium

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas19.3 ± 0.2kcal/molReviewCox, Wagman, et al., 1984CODATA Review value
Δfgas19.34kcal/molReviewChase, 1998Data last reviewed in December, 1983
Quantity Value Units Method Reference Comment
gas,1 bar40.6534 ± 0.0007cal/mol*KReviewCox, Wagman, et al., 1984CODATA Review value
gas,1 bar40.652cal/mol*KReviewChase, 1998Data last reviewed in December, 1983

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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View table.

Temperature (K) 970.385 to 1800.1800. to 6000.
A 4.93299017.71890
B 0.110379-9.377290
C -0.1182642.367961
D 0.041508-0.162393
E 0.001048-8.398901
F 17.864401.187331
G 46.6009151.21881
H 19.3356019.33560
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1983 Data last reviewed in December, 1983

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfliquid0.521kcal/molReviewChase, 1998Data last reviewed in December, 1983
Quantity Value Units Method Reference Comment
liquid,1 bar20.02cal/mol*KReviewChase, 1998Data last reviewed in December, 1983
Quantity Value Units Method Reference Comment
solid,1 bar18.35 ± 0.072cal/mol*KReviewCox, Wagman, et al., 1984CODATA Review value
Quantity Value Units Method Reference Comment
solid18.35cal/mol*KReviewChase, 1998Data last reviewed in December, 1983

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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View table.

Temperature (K) 312.65 to 970.385
A 8.484052
B -3.076819
C 2.043511
D -0.000676
E -0.000028
F -1.888860
G 31.11370
H 0.521989
ReferenceChase, 1998
Comment Data last reviewed in December, 1983

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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View table.

Temperature (K) 298. to 312.65
A 2.257711
B 15.60990
C 10.87770
D -6.402871
E -0.025748
F -1.536691
G 15.85700
H 0.000000
ReferenceChase, 1998
Comment Data last reviewed in December, 1983

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(Bromine anion • 4294967295rubidium) + rubidium = Bromine anion

By formula: (Br- • 4294967295Rb) + Rb = Br-

Quantity Value Units Method Reference Comment
Δr26.6 ± 1.0kcal/molTherMiller, Leopold, et al., 1986gas phase; Extrapolated by polarizability and radius from experimental data.

(CAS Reg. No. 106070-95-5 • 4294967295rubidium) + rubidium = CAS Reg. No. 106070-95-5

By formula: (CAS Reg. No. 106070-95-5 • 4294967295Rb) + Rb = CAS Reg. No. 106070-95-5

Quantity Value Units Method Reference Comment
Δr32.22 ± 0.25kcal/molN/AMiller, Leopold, et al., 1986gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to Rb+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)4.17713 ± 0.000002eVN/AN/AL

Electron affinity determinations

EA (eV) Method Reference Comment
0.485940 ± 0.000044LPDFrey, Breyer, et al., 1978Given: 3919.18(16) cm-1; B
0.4860 ± 0.0030LPESPatterson, Hotop, et al., 1974B

Ionization energy determinations

IE (eV) Method Reference Comment
4.17713EVALLide, 1992LL
4.18PEWilliams and Potts, 1976LLK
4.17713 ± 0.000002SMoore, 1970RDSH

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

(Bromine anion • 4294967295rubidium) + rubidium = Bromine anion

By formula: (Br- • 4294967295Rb) + Rb = Br-

Quantity Value Units Method Reference Comment
Δr26.6 ± 1.0kcal/molTherMiller, Leopold, et al., 1986gas phase; Extrapolated by polarizability and radius from experimental data.

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A., CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Miller, Leopold, et al., 1986
Miller, T.M.; Leopold, D.G.; Murray, K.K.; Lineberger, W.C., Electron Affinities of the Alkali Halides and the Structure of their Negative Ions, J. Chem. Phys., 1986, 85, 5, 2368, https://doi.org/10.1063/1.451091 . [all data]

Frey, Breyer, et al., 1978
Frey, P.; Breyer, F.; Hotop, H., High Resolutions Photodetachment from the Rubidium Negative Ion around the Rb(5p1/2) Threshold, J. Phys. B: Atom. Mol. Phys., 1978, 11, 19, L589, https://doi.org/10.1088/0022-3700/11/19/005 . [all data]

Patterson, Hotop, et al., 1974
Patterson, T.A.; Hotop, H.; Kasdan, A.; Norcross, D.W.; Lineberger, W.C., Resonances in Alkali Negative-Ion Photodetachment and Electron Affinities of the Corresponding Neutrals, Phys. Rev. Lett., 1974, 32, 5, 189, https://doi.org/10.1103/PhysRevLett.32.189 . [all data]

Lide, 1992
Lide, D.R. (Editor), Ionization potentials of atoms and atomic ions in Handbook of Chem. and Phys., 1992, 10-211. [all data]

Williams and Potts, 1976
Williams, T.A.; Potts, A.W., Complexities in the HeI photoelectron spectra of alkali metal vapours, J. Electron Spectrosc. Relat. Phenom., 1976, 8, 331. [all data]

Moore, 1970
Moore, C.E., Ionization potentials and ionization limits derived from the analyses of optical spectra, Natl. Stand. Ref. Data Ser., (U.S. Natl. Bur. Stand.), 1970, 34, 1. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References