Dimethylarsine
- Formula: C2H7As
- Molecular weight: 105.9986
- CAS Registry Number: 593-57-7
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.1 | PE | Elbel, Dieck, et al., 1982 | LBLHLM |
| 8.58 | PE | Cullen, Frost, et al., 1972 | LLK |
| 9.0 ± 0.1 | EI | Cullen and Frost, 1962 | RDSH |
| 8.87 | PE | Elbel, Dieck, et al., 1982 | Vertical value; LBLHLM |
| 8.65 | PE | Starzewski, Richter, et al., 1976 | Vertical value; LLK |
| 9.14 | PE | Cowley, Dewar, et al., 1974 | Vertical value; LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Elbel, Dieck, et al., 1982
Elbel, S.; Dieck, H.T.; Demuth, R.,
Photoelectron sSpectra of group V compounds. IX. The relative perfluoroalkyl substituent effect,
J. Fluorine Chem., 1982, 19, 349. [all data]
Cullen, Frost, et al., 1972
Cullen, W.R.; Frost, D.C.; Leeder, W.R.,
The ultraviolet and photoelectron spectra of some unsaturated fluorocarbon derivatives,
J. Fluorine Chem., 1972, 1, 227. [all data]
Cullen and Frost, 1962
Cullen, W.R.; Frost, D.C.,
Ionization potentials of some perfluoroalkyl arsines,
Can. J. Chem., 1962, 40, 390. [all data]
Starzewski, Richter, et al., 1976
Starzewski, K.-H.A.O.; Richter, W.; Schmidbaur, H.,
Photoelektronenspektren und Struktur von Arsenyliden. P versus As: Ein Beitrag zur Problematik der ylidischen Bindung,
Chem. Ber., 1976, 109, 473. [all data]
Cowley, Dewar, et al., 1974
Cowley, A.H.; Dewar, M.J.S.; Goodman, D.W.; Padolina, M.C.,
Detection of rotational isomerism in diphosphines and diarsines by photoelectron spectroscopy,
J. Am. Chem. Soc., 1974, 96, 2648. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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