2-Tridecanone

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil536.2KN/AWeast and Grasselli, 1989BS
Tboil528.15KN/ADakin, 1910Uncertainty assigned by TRC = 2. K; TRC
Tboil535.65KN/AMasson, 1909Uncertainty assigned by TRC = 2. K; TRC
Tboil535.9KN/AKrafft, 1882Uncertainty assigned by TRC = 2. K; TRC
Tboil536.15KN/AKrafft, 1879Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Tc717.0KN/APulliam, Gude, et al., 1995Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
ρc1.22mol/lN/APulliam, Gude, et al., 1995Uncertainty assigned by TRC = 0.04 mol/l; TRC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
407.20.013Aldrich Chemical Company Inc., 1990BS
433.20.021Weast and Grasselli, 1989BS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
69.6350.AStephenson and Malanowski, 1987Based on data from 335. to 534. K.; AC
61.439.AStephenson and Malanowski, 1987Based on data from 424. to 510. K.; AC
49.6541.N/AAmbrose, Ellender, et al., 1975Based on data from 400. to 628. K.; AC
69.8348.EBMeyer and Wagner, 1966Based on data from 335. to 431. K.; AC
62.1375.N/AStull, 1947Based on data from 360. to 535. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
360.0 to 535.75.288822638.443-36.70Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Dakin, 1910
Dakin, H.D., A general reaction for the conversion of saturated fatty acids (r.ch(2).ch( 2).cooh) into ketones (r.co.ch(3)), Am. Chem. J., 1910, 44, 41. [all data]

Masson, 1909
Masson, H., C. R. Hebd. Seances Acad. Sci., 1909, 149, 630. [all data]

Krafft, 1882
Krafft, F., On Nineteen Higher Normal Paraffins and a Simple Volume Law for Liquids that form Drops I., Ber. Dtsch. Chem. Ges., 1882, 15, 1687-711. [all data]

Krafft, 1879
Krafft, F., Lauric acid and its transformation to undecylic acid, Ber. Dtsch. Chem. Ges., 1879, 12, 1664-8. [all data]

Pulliam, Gude, et al., 1995
Pulliam, M.K.; Gude, M.T.; Teja, A.S., Critical Temperatures and Densities of n-Alkanones, J. Chem. Eng. Data, 1995, 40, 455-8. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Ambrose, Ellender, et al., 1975
Ambrose, D.; Ellender, J.H.; Lees, E.B.; Sprake, C.H.S.; Townsend, R., Thermodynamic properties of organic oxygen compounds XXXVIII. Vapour pressures of some aliphatic ketones, The Journal of Chemical Thermodynamics, 1975, 7, 5, 453-472, https://doi.org/10.1016/0021-9614(75)90275-X . [all data]

Meyer and Wagner, 1966
Meyer, Edwin F.; Wagner, Robert E., Cohesive Energies in Polar Organic Liquids, J. Phys. Chem., 1966, 70, 10, 3162-3168, https://doi.org/10.1021/j100882a025 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]


Notes

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