Sucrose

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-2221.2kJ/molCcbClarke and Stegeman, 1939ALS
Quantity Value Units Method Reference Comment
Δcsolid-5643.4 ± 1.8kJ/molCcbPonomarev and Migarskaya, 1960Reanalyzed by Cox and Pilcher, 1970, Original value = -5645.9 ± 1.8 kJ/mol; Corresponding Δfsolid = -2222.9 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-5644.17kJ/molCcbClarke and Stegeman, 1939Corresponding Δfsolid = -2222.1 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-5637.4 ± 1.7kJ/molCcbHuffman and Ellis, 1935Reanalyzed by Cox and Pilcher, 1970, Original value = -5642.21 kJ/mol; Corresponding Δfsolid = -2228.9 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-5664.38 ± 0.69kJ/molCcbWrede, 1911See Fischer and Wrede, 1904; Corresponding Δfsolid = -2201.87 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar392.40J/mol*KN/APutnam and Boerio-Goates, 1993DH
solid,1 bar360.2J/mol*KN/AParks, Huffman, et al., 1933Extrapolation below 90 K, 113.2 J/mol*K.; DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
424.30298.15Putnam and Boerio-Goates, 1993T = 10 to 340 K.; DH
430.300.Finegold, Franks, et al., 1989T(glass) = 330 K.; DH
425.5298.15Anderson, Higbie, et al., 1950T = 298 to 363 K.; DH
422.50297.0Parks, Huffman, et al., 1933T = 94 to 297 K. Value is unsmoothed experimental datum.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Clarke and Stegeman, 1939
Clarke, T.H.; Stegeman, G., Heats of combustion of some mono- and disaccharides, J. Am. Chem. Soc., 1939, 61, 1726-1730. [all data]

Ponomarev and Migarskaya, 1960
Ponomarev, V.V.; Migarskaya, L.B., Heats of combustion of some amino-acids, Russ. J. Phys. Chem. (Engl. Transl.), 1960, 34, 1182-1183. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Huffman and Ellis, 1935
Huffman, H.M.; Ellis, E.L., Thermal Data. II. The heats of combustion of l-cysteine, of l-cystine, β-thiolactic acid and β,β'-dithiodilactic acid, J. Am. Chem. Soc., 1935, 57, 41-46. [all data]

Wrede, 1911
Wrede, F., Uber die Bestimmung von Berbrennungswarmen mittels der kalorimetrischen Bombe unter Benutzung des Platinwiderstandsthermometers, Z. Phys. Chem. (Leipzig), 1911, 81-94. [all data]

Fischer and Wrede, 1904
Fischer, E.; Wrede, F., Uber die Verbrennungswarme einiger organischer Verbindungen, Sitzungsber. Dtsch. Akad. Wiss. Berlin Kl. Math. Phys. Tech., 1904, 687-715. [all data]

Putnam and Boerio-Goates, 1993
Putnam, R.L.; Boerio-Goates, J., Heat capacity measurements and thermodynamic functions of crystalline sucrose at temepratures from 5 to 342 K. Revised values for _fG°m(sucrose, cr, 298.15 K), _fG°m(sucrose, aq, 298.15 K), S°m(sucrose, aq, 298.15 K); and _rG°m(298.15 K) for the hydrolysis of aqueous sucrose, J. Chem. Thermodynam., 1993, 25(5), 607-613. [all data]

Parks, Huffman, et al., 1933
Parks, G.S.; Huffman, H.M.; Barmore, M., Thermal data on organic compounds. XI. The heat capacities, entropies and free energies of ten compounds containing oxygen or nitrogen. J. Am. Chem. Soc., 1933, 55, 2733-2740. [all data]

Finegold, Franks, et al., 1989
Finegold, L.; Franks, F.; Hatley, R.H.M., Glass/rubber transitions and heat capacities of binary sugar blends, J. Chem. Soc., Faraday Trans., 1989, 1 85(9), 2945-2951. [all data]

Anderson, Higbie, et al., 1950
Anderson, G.L., Jr.; Higbie, H.; Stegeman, G., The heat capacity of sucrose from 25 to 90°C, J. Am. Chem. Soc., 1950, 72, 3798-3799. [all data]


Notes

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