Copper, bis(2,2,6-trimethyl-3,5-heptanedionato-O,O')-


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub130.2 ± 0.7kJ/molN/ARibeiro da Silva, 1995 
Δsub130.6 ± 1.5kJ/molN/ARibeiro da Silva, 1995 
Δsub131.7 ± 1.3kJ/molN/ARibeiro da Silva, 1995 
Δsub126.4 ± 1.1kJ/molN/ARibeiro Da Silva, Ribeiro Da Silva, et al., 1984 

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
127.4 ± 0.7354.MERibeiro da Silva, 1995Based on data from 346. to 362. K.
127.8 ± 1.5354.TERibeiro da Silva, 1995Based on data from 346. to 362. K.
129.0 ± 1.3351.MERibeiro da Silva, 1995 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ribeiro da Silva, 1995
Ribeiro da Silva, M., Vapour pressures and standard molar enthalpies of sublimation of seven crystalline copper(II) β-diketonates. The mean molar (Cu-O) bond-dissociation enthalpies, The Journal of Chemical Thermodynamics, 1995, 27, 2, 175-190, https://doi.org/10.1006/jcht.1995.0014 . [all data]

Ribeiro Da Silva, Ribeiro Da Silva, et al., 1984
Ribeiro Da Silva, Manuel A.V.; Ribeiro Da Silva, Maria D.M.C.; Carvalho, Ana P.S.M.C.; Akello, Margaret J.; Pilcher, Geofrey, Standard enthalpies of formation of bis(pentane-2,4-dionato)Cu(II) and of four bis(methyl-substituted heptane-3,5-dionato)Cu(II) complexes: the mean (Cu«58872»O) bond-dissociation enthalpies, The Journal of Chemical Thermodynamics, 1984, 16, 2, 137-144, https://doi.org/10.1016/0021-9614(84)90146-0 . [all data]


Notes

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