Sulfur, pentafluoro(trifluoromethyl)-, (OC-6-21)-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner)

Gas basicity at 298K

Gas basicity (review) (kJ/mol) Reference Comment
640. ± 10.Pepi, Ricci, et al., 2005T = 298K; PA(SF5CH3) bracketed between COS and CH3Cl based on dissociative PT reactions with large entropy changes, that may affect the kinetics. However, the derived PA agrees with ab initio values.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pepi, Ricci, et al., 2005
Pepi, F.; Ricci, A.; Di Stefano, M.; Rosi, M., Gas phase protonation of trifluoromethyl sulfur pentafluoride, Phys. Chem. Chem. Phys., 2005, 7, 1181. [all data]


Notes

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