Carbon monosulfide


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas67.000kcal/molReviewChase, 1998Data last reviewed in December, 1976
Quantity Value Units Method Reference Comment
gas,1 bar50.323cal/mol*KReviewChase, 1998Data last reviewed in December, 1976

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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View table.

Temperature (K) 298. to 600.600. to 6000.
A 5.2016908.240251
B 5.9748810.708952
C -1.934891-0.227228
D -1.0908100.027179
E 0.030204-0.238404
F 65.3042163.82110
G 55.1027059.05189
H 67.0001067.00010
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1976 Data last reviewed in December, 1976

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Ion clustering data, Constants of diatomic molecules, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Iron ion (1+) + Carbon monosulfide = (Iron ion (1+) • Carbon monosulfide)

By formula: Fe+ + CS = (Fe+ • CS)

Quantity Value Units Method Reference Comment
Δr49.5 ± 3.1kcal/molCIDTRodgers and Armentrout, 2000 
Δr55.2 ± 2.8kcal/molCIDTSchroeder, Kretzschmar, et al., 1999 

Cobalt ion (1+) + Carbon monosulfide = (Cobalt ion (1+) • Carbon monosulfide)

By formula: Co+ + CS = (Co+ • CS)

Quantity Value Units Method Reference Comment
Δr61.7 ± 7.8kcal/molCIDTRue, Armentrout, et al., 2001 
Δr57.4 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Chromium ion (1+) + Carbon monosulfide = (Chromium ion (1+) • Carbon monosulfide)

By formula: Cr+ + CS = (Cr+ • CS)

Quantity Value Units Method Reference Comment
Δr38.9 ± 1.4kcal/molCIDTRue, Armentrout, et al., 2001, 2 
Δr37.8 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Manganese ion (1+) + Carbon monosulfide = (Manganese ion (1+) • Carbon monosulfide)

By formula: Mn+ + CS = (Mn+ • CS)

Quantity Value Units Method Reference Comment
Δr19.1 ± 5.1kcal/molCIDTRue, Armentrout, et al., 2001, 2 
Δr18.6 ± 3.3kcal/molCIDTRodgers and Armentrout, 2000 

Molybdenum ion (1+) + Carbon monosulfide = (Molybdenum ion (1+) • Carbon monosulfide)

By formula: Mo+ + CS = (Mo+ • CS)

Quantity Value Units Method Reference Comment
Δr38.7 ± 3.2kcal/molCIDTSchroeder, Kretzschmar, et al., 2003 
Δr38.7 ± 4.3kcal/molCIDTRodgers and Armentrout, 2000 

Titanium ion (1+) + Carbon monosulfide = (Titanium ion (1+) • Carbon monosulfide)

By formula: Ti+ + CS = (Ti+ • CS)

Quantity Value Units Method Reference Comment
Δr36.8 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000 

Scandium ion (1+) + Carbon monosulfide = (Scandium ion (1+) • Carbon monosulfide)

By formula: Sc+ + CS = (Sc+ • CS)

Quantity Value Units Method Reference Comment
Δr31.8 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000 

Zirconium ion (1+) + Carbon monosulfide = (Zirconium ion (1+) • Carbon monosulfide)

By formula: Zr+ + CS = (Zr+ • CS)

Quantity Value Units Method Reference Comment
Δr61.7 ± 2.6kcal/molCIDTRodgers and Armentrout, 2000 

Silver ion (1+) + Carbon monosulfide = (Silver ion (1+) • Carbon monosulfide)

By formula: Ag+ + CS = (Ag+ • CS)

Quantity Value Units Method Reference Comment
Δr36.3 ± 4.8kcal/molCIDTRodgers and Armentrout, 2000 

Vanadium ion (1+) + Carbon monosulfide = (Vanadium ion (1+) • Carbon monosulfide)

By formula: V+ + CS = (V+ • CS)

Quantity Value Units Method Reference Comment
Δr39.2 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000 

Yttrium ion (1+) + Carbon monosulfide = (Yttrium ion (1+) • Carbon monosulfide)

By formula: Y+ + CS = (Y+ • CS)

Quantity Value Units Method Reference Comment
Δr32.7 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000 

Nickel ion (1+) + Carbon monosulfide = (Nickel ion (1+) • Carbon monosulfide)

By formula: Ni+ + CS = (Ni+ • CS)

Quantity Value Units Method Reference Comment
Δr56.4 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Zinc ion (1+) + Carbon monosulfide = (Zinc ion (1+) • Carbon monosulfide)

By formula: Zn+ + CS = (Zn+ • CS)

Quantity Value Units Method Reference Comment
Δr33.7 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Copper ion (1+) + Carbon monosulfide = (Copper ion (1+) • Carbon monosulfide)

By formula: Cu+ + CS = (Cu+ • CS)

Quantity Value Units Method Reference Comment
Δr55.9 ± 2.4kcal/molCIDTRodgers and Armentrout, 2000 

Niobium ion (1+) + Carbon monosulfide = (Niobium ion (1+) • Carbon monosulfide)

By formula: Nb+ + CS = (Nb+ • CS)

Quantity Value Units Method Reference Comment
Δr57.8 ± 2.6kcal/molCIDTRodgers and Armentrout, 2000 

Ruthenium ion (1+) + Carbon monosulfide = (Ruthenium ion (1+) • Carbon monosulfide)

By formula: Ru+ + CS = (Ru+ • CS)

Quantity Value Units Method Reference Comment
Δr60.5 ± 4.8kcal/molCIDTRodgers and Armentrout, 2000 

Palladium ion (1+) + Carbon monosulfide = (Palladium ion (1+) • Carbon monosulfide)

By formula: Pd+ + CS = (Pd+ • CS)

Quantity Value Units Method Reference Comment
Δr47.8 ± 3.3kcal/molCIDTRodgers and Armentrout, 2000 

Rh+ + Carbon monosulfide = (Rh+ • Carbon monosulfide)

By formula: Rh+ + CS = (Rh+ • CS)

Quantity Value Units Method Reference Comment
Δr55.9 ± 4.5kcal/molCIDTRodgers and Armentrout, 2000 

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Constants of diatomic molecules, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to CS+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)11.33 ± 0.01eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)189.2kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity182.kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Δf(+) ion327.kcal/molN/AN/A 
Quantity Value Units Method Reference Comment
ΔfH(+) ion,0K324.kcal/molN/AN/A 

Electron affinity determinations

EA (eV) Method Reference Comment
0.205 ± 0.021LPESBurnett, Feigerle, et al., 1982B
>1.60 ± 0.30EIAEThynne, 1972From COS; B

Ionization energy determinations

IE (eV) Method Reference Comment
11.335EVALHuber and Herzberg, 1979LLK
11.0 ± 0.03EITal'roze, Butkovskaya, et al., 1978LLK
11.33 ± 0.01PIDrowart, Smets, et al., 1978LLK
11.4 ± 0.1EIHildenbrand, 1975LLK
11.33 ± 0.02PEKing, Kroto, et al., 1972LLK
11.33 ± 0.01PEJonathan, Morris, et al., 1972LLK
11.33 ± 0.02PEJonathan, Morris, et al., 1972, 2LLK
11.39 ± 0.10EIHildenbrand, 1972LLK
11.34 ± 0.02PEFrost, Lee, et al., 1972LLK
~11.65SDonovan, Husain, et al., 1970RDSH
11.71 ± 0.03DERDibeler and Walker, 1967RDSH
11.8 ± 0.2EIBlanchard and LeGoff, 1957RDSH

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Constants of diatomic molecules, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Silver ion (1+) + Carbon monosulfide = (Silver ion (1+) • Carbon monosulfide)

By formula: Ag+ + CS = (Ag+ • CS)

Quantity Value Units Method Reference Comment
Δr36.3 ± 4.8kcal/molCIDTRodgers and Armentrout, 2000 

Cobalt ion (1+) + Carbon monosulfide = (Cobalt ion (1+) • Carbon monosulfide)

By formula: Co+ + CS = (Co+ • CS)

Quantity Value Units Method Reference Comment
Δr61.7 ± 7.8kcal/molCIDTRue, Armentrout, et al., 2001 
Δr57.4 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Chromium ion (1+) + Carbon monosulfide = (Chromium ion (1+) • Carbon monosulfide)

By formula: Cr+ + CS = (Cr+ • CS)

Quantity Value Units Method Reference Comment
Δr38.9 ± 1.4kcal/molCIDTRue, Armentrout, et al., 2001, 2 
Δr37.8 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Copper ion (1+) + Carbon monosulfide = (Copper ion (1+) • Carbon monosulfide)

By formula: Cu+ + CS = (Cu+ • CS)

Quantity Value Units Method Reference Comment
Δr55.9 ± 2.4kcal/molCIDTRodgers and Armentrout, 2000 

Iron ion (1+) + Carbon monosulfide = (Iron ion (1+) • Carbon monosulfide)

By formula: Fe+ + CS = (Fe+ • CS)

Quantity Value Units Method Reference Comment
Δr49.5 ± 3.1kcal/molCIDTRodgers and Armentrout, 2000 
Δr55.2 ± 2.8kcal/molCIDTSchroeder, Kretzschmar, et al., 1999 

Manganese ion (1+) + Carbon monosulfide = (Manganese ion (1+) • Carbon monosulfide)

By formula: Mn+ + CS = (Mn+ • CS)

Quantity Value Units Method Reference Comment
Δr19.1 ± 5.1kcal/molCIDTRue, Armentrout, et al., 2001, 2 
Δr18.6 ± 3.3kcal/molCIDTRodgers and Armentrout, 2000 

Molybdenum ion (1+) + Carbon monosulfide = (Molybdenum ion (1+) • Carbon monosulfide)

By formula: Mo+ + CS = (Mo+ • CS)

Quantity Value Units Method Reference Comment
Δr38.7 ± 3.2kcal/molCIDTSchroeder, Kretzschmar, et al., 2003 
Δr38.7 ± 4.3kcal/molCIDTRodgers and Armentrout, 2000 

Niobium ion (1+) + Carbon monosulfide = (Niobium ion (1+) • Carbon monosulfide)

By formula: Nb+ + CS = (Nb+ • CS)

Quantity Value Units Method Reference Comment
Δr57.8 ± 2.6kcal/molCIDTRodgers and Armentrout, 2000 

Nickel ion (1+) + Carbon monosulfide = (Nickel ion (1+) • Carbon monosulfide)

By formula: Ni+ + CS = (Ni+ • CS)

Quantity Value Units Method Reference Comment
Δr56.4 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Palladium ion (1+) + Carbon monosulfide = (Palladium ion (1+) • Carbon monosulfide)

By formula: Pd+ + CS = (Pd+ • CS)

Quantity Value Units Method Reference Comment
Δr47.8 ± 3.3kcal/molCIDTRodgers and Armentrout, 2000 

Rh+ + Carbon monosulfide = (Rh+ • Carbon monosulfide)

By formula: Rh+ + CS = (Rh+ • CS)

Quantity Value Units Method Reference Comment
Δr55.9 ± 4.5kcal/molCIDTRodgers and Armentrout, 2000 

Ruthenium ion (1+) + Carbon monosulfide = (Ruthenium ion (1+) • Carbon monosulfide)

By formula: Ru+ + CS = (Ru+ • CS)

Quantity Value Units Method Reference Comment
Δr60.5 ± 4.8kcal/molCIDTRodgers and Armentrout, 2000 

Scandium ion (1+) + Carbon monosulfide = (Scandium ion (1+) • Carbon monosulfide)

By formula: Sc+ + CS = (Sc+ • CS)

Quantity Value Units Method Reference Comment
Δr31.8 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000 

Titanium ion (1+) + Carbon monosulfide = (Titanium ion (1+) • Carbon monosulfide)

By formula: Ti+ + CS = (Ti+ • CS)

Quantity Value Units Method Reference Comment
Δr36.8 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000 

Vanadium ion (1+) + Carbon monosulfide = (Vanadium ion (1+) • Carbon monosulfide)

By formula: V+ + CS = (V+ • CS)

Quantity Value Units Method Reference Comment
Δr39.2 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000 

Yttrium ion (1+) + Carbon monosulfide = (Yttrium ion (1+) • Carbon monosulfide)

By formula: Y+ + CS = (Y+ • CS)

Quantity Value Units Method Reference Comment
Δr32.7 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000 

Zinc ion (1+) + Carbon monosulfide = (Zinc ion (1+) • Carbon monosulfide)

By formula: Zn+ + CS = (Zn+ • CS)

Quantity Value Units Method Reference Comment
Δr33.7 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Zirconium ion (1+) + Carbon monosulfide = (Zirconium ion (1+) • Carbon monosulfide)

By formula: Zr+ + CS = (Zr+ • CS)

Quantity Value Units Method Reference Comment
Δr61.7 ± 2.6kcal/molCIDTRodgers and Armentrout, 2000 

Constants of diatomic molecules

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through October, 1976

Symbols used in the table of constants
SymbolMeaning
State electronic state and / or symmetry symbol
Te minimum electronic energy (cm-1)
ωe vibrational constant – first term (cm-1)
ωexe vibrational constant – second term (cm-1)
ωeye vibrational constant – third term (cm-1)
Be rotational constant in equilibrium position (cm-1)
αe rotational constant – first term (cm-1)
γe rotation-vibration interaction constant (cm-1)
De centrifugal distortion constant (cm-1)
βe rotational constant – first term, centrifugal force (cm-1)
re internuclear distance (Å)
Trans. observed transition(s) corresponding to electronic state
ν00 position of 0-0 band (units noted in table)
Diatomic constants for 12C32S
StateTeωeωexeωeyeBeαeγeDeβereTrans.ν00
Fragments of further band systems and Rydberg series
missing citation
G (81373) [1229]         G ← X 81347
missing citation
F           F ← X 77537
missing citation
Continuous absorption to a repulsive state; 74600 - 76300 cm-1.
missing citation
StateTeωeωexeωeyeBeαeγeDeβereTrans.ν00
E (71890) [1459] H         (E ← X) (V) 71979 H
missing citation
c (3Σ+)           c ← X 1 71803 H
missing citation
C (1Σ+) (71255) [1425] H         C ← X 2 71327 H
missing citation
B (1Σ+) (64868) [1332] H         (B ← X) (V) 64893 H
missing citation
StateTeωeωexeωeyeBeαeγeDeβereTrans.ν00
A' 1Σ+ 56505 462.4 H 7.46 3 -0.108 0.5114 0.0109 4  (2.5E-6)  1.944 A' → X R 56093 H
missing citation
x, yFragments of two perturbing states (Bx<0.61, By<0.77) near 39170 and 39950 cm-1.
Barrow, Dixon, et al., 1961
A new band at 39138 cm-1, originally Field and Bergeman, 1971 attributed to a 3Δ state, is now believed to be due to v=11 of a 3Π Bruna, Kammer, et al., 1975.
A 1Π 38904.4 1073.4 5 Z 10.1  0.7800 5 6 $I 0.0063 -0.0004 (1.65E-6)  1.5739 A ↔ X 7 8 R 38797.6 Z
missing citation; missing citation
StateTeωeωexeωeyeBeαeγeDeβereTrans.ν00
e 3Σ- 38683 752 9 4.7  0.6194 9 0.0040  (1.68E-6)  1.766 e ← X R 38417 9
missing citation
d 3ΔI 11 35675.0 795.6 10 4.91  0.6367 10 0.0061  (1.63E-6)  1.7420 d ← X R 35430.6 10
missing citation; Field and Bergeman, 1971; Cossart and Bergeman, 1976
a' 3Σ+ 31331.4 830.7 10 5.04  0.6489 10 12 0.0060  (1.58E-6)  1.7255 a' ← X R 31104.6 10
missing citation; Field and Bergeman, 1971; Cossart and Bergeman, 1976
Unclassified emission bands, probably due to triplet - triplet transitions, in the region 13300 - 22200 cm-1.
missing citation
StateTeωeωexeωeyeBeαeγeDeβereTrans.ν00
a 3Πr 27661.0 13 1135.1 10 7.73  0.7851 10 0.0072  [1.94E-6] 14  1.5687 a → X 15 R 27585.7 10
Tewarson and Palmer, 1968; missing citation; Cossart and Bergeman, 1976
X 1Σ+ 0 1285.08 Z 6.46  0.8200462 $I 0.0059224  1.43E-6  1.534941 16  
Mockler and Bird, 1955; Kewley, Sastry, et al., 1963; Lovas and Krupenie, 1974

Notes

1Single weak absorption band.
2Bands described as diffuse.
3ωeze = -0.0377.
4αv= +0.00112(v+1/2)2 - 0.000208(v+1/2)3.
5Deperturbed constants Barrow, Dixon, et al., 1961; all observed vibrational levels of this state are strongly perturbed by interactions with a 3Π, a' 3Σ+, d 3Δ, e 3Σ- Lagerqvist, Westerlund, et al., 1959, Barrow, Dixon, et al., 1961, Field and Bergeman, 1971. The following rather different set of deperturbed parameters is given by Cossart and Bergeman, 1976; Te = 38895.7 Cossart and Bergeman, 1976, ωe = 1077.3 Cossart and Bergeman, 1976, ωexe = 10.66 Cossart and Bergeman, 1976, Be = 0.7881 Cossart and Bergeman, 1976, αe = 0.0092 Cossart and Bergeman, 1976.
6Λ-doubling intervals in v=0 (J=1-9) range from 0.00045 to 0.05961cm-1 Silvers, Bergeman, et al., 1970, Field and Bergeman, 1971. The variation with J of the Stark effect was observed in optical-rf double resonance and was analyzed Field and Bergeman, 1971 to give μel(v=0) = 0.63 D (+CS-); see also Silvers, Bergeman, et al., 1970.
7Lifetimes from Hanle effect observations τ(v=0) = 176 ns Silvers and Chiu, 1972 (corrected for lengthening by triplet mixing), τ(v=2) = 203 ns Silvers and Chiu, 1972. The phase shift method Smith, 1969 gives τ(v=0) = 255 ns Smith, 1969, τ(v=1) = 339 ns Smith, 1969, τ(v ≥ 2) = 292 ns Smith, 1969; f00 = 0.0059.
8Morse-potential Franck-Condon factors Felenbok, 1965: compare with experimental values from the fluorescence spectrum excited in the VUV photolysis of CS2 and OCS Lee and Judge, 1975. C34S isotopic bands Narasimham and Gopal, 1966, Chaudhry, Upadhya, et al., 1970.
9Only v=1 and 2 observed Barrow, Dixon, et al., 1961; the vibrational numbering is from isotope studies Field and Bergeman, 1971. The following set of deperturbed parameters is given by Cossart and Bergeman, 1976; Te = 38681.9, ωe = 752.8, ωexe = 4.95, Be = 0.6227, αe = 0.0062. Spin-splitting in v=1: λ+1/2γ = 1.75 Barrow, Dixon, et al., 1961.
10Deperturbed constants Cossart and Bergeman, 1976.
11This state, originally Barrow, Dixon, et al., 1961, Field and Bergeman, 1971 considered to be 3Π and labelled k, is now believed to be 3Δ Robbe and Schamps, 1972, Bruna, Kammer, et al., 1975. The name has been changed to d 3Δ in order to emphasize the similarity to CO. A ~ -50.
12Spin-splitting constant λ(v=10) = -1.28 Field and Bergeman, 1971.
13A ~ 95 cm-1.
14From Taylor, Setser, et al., 1972.
15Two subbands corresponding to 3Π1 - 3Σ+ and 3Π0 - 3Σ+ have been observed Taylor, Setser, et al., 1972.
16Microwave sp. 20
17From a short extrapolation of the vibrational levels in A 1Σ+ Bell, Ng, et al., 1972, assuming that the atomic products arising at the dissociation limit are C, 3P2 + S, 3P2. The latest thermochemical (mass-spectrometric) value is D00= 7.21 eV Hildenbrand, 1972. Both values agree with an upper limit (< 7.7 eV) derived from infrared chemiluminescence studies Hancock, Morley, et al., 1971, and the corresponding heats of formation, ΔHof0 = 66.11 or 69.5 kcal/mole, respectively, are supported by photodissociation Okabe, 1972 and photoionization Dibeler and Walker, 1967, 2 results for CS2. See, however, Hubin-Franskin, Locht, et al., 1976, Hubin-Franskin, Katihabwa, et al., 1976 who suggest ΔHof0 = 33 kcal/mole, implying D00 = 8.79 eV.
18From the photoelectron spectrum Jonathan, Morris, et al., 1972, King, Kroto, et al., 1972, Frost, Lee, et al., 1972.
19RKR potential functions Nair, Singh, et al., 1965.
20Dipole moments [-CS+, see McGurk, Tigleaar, et al., 1973] from Stark effect μel(v=0) = 1.958 D Winnewisser and Cook, 1968, μel(v=1) = 1.936 D Winnewisser and Cook, 1968. Zeeman effect McGurk, Tigleaar, et al., 1973, molecular g factor -0.2702. 32S/33S and 32S/34S mass ratios from microwave spectra Rosenblum, Townes, et al., 1958.
21D00(CS) + I.P.(S) - I.P.(CS).
22From the photoelectron spectrum Frost, Lee, et al., 1972: see also Jonathan, Morris, et al., 1972.
23A = -298.46 Horani, 1979.
24From the photoelectron spectrum Frost, Lee, et al., 1972; Jonathan, Morris, et al., 1972 and King, Kroto, et al., 1972 give 1330 and 1290 cm-1, respectively. Only one level has been found in the optical spectrum Horani, 1979.
25Spin-splitting constant γ0 = +0.0201.

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Schroeder, Kretzschmar, et al., 1999
Schroeder, D.; Kretzschmar, I.; Schwarz; Rue, C.; Armentrout, P.B., On the Structural Dichotomy of Cationic, Anionic, and Neutral FeS2, Inorg. Chem., 1999, 38, 15, 3474, https://doi.org/10.1021/ic990241b . [all data]

Rue, Armentrout, et al., 2001
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H., Guided Ion Beam Studies of the Reactions of Fe+ and Co+ With CS2 and COS, J. Phys. Chem. A, 2001, 105, 37, 8456, https://doi.org/10.1021/jp0120716 . [all data]

Rue, Armentrout, et al., 2001, 2
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H., Guided Ion Beam Studies of the Reactions of the State-Specific Reactions of Cr+ and Mn+ with CS2 and COS, Int. J. Mass Spectrom., 2001, 210/211, 283, https://doi.org/10.1016/S1387-3806(01)00400-6 . [all data]

Schroeder, Kretzschmar, et al., 2003
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Notes

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