Trichlorosilyl

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   H
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 43700 T gas Irikura, Johnson, et al., 1992
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
2 Umbrella 282 ± 30 gas MPI Irikura, Johnson, et al., 1992

State:   G
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 43700 T gas Irikura, Johnson, et al., 1992
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
2 Umbrella 261 ± 15 gas MPI Irikura, Johnson, et al., 1992

State:   F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 43700 T gas Irikura, Johnson, et al., 1992
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
2 Umbrella 262 ± 16 gas MPI Irikura, Johnson, et al., 1992

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 SiCl stretch 470 m Ar IR Jacox and Milligan, 1968
Miller and Andrews, 1981
e 3 SiCl stretch 582 vs Ar IR Jacox and Milligan, 1968
Miller and Andrews, 1981

Additional references: Jacox, 1994, page 218; Leray and Roncin, 1965

Notes

mMedium
vsVery strong
TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Irikura, Johnson, et al., 1992
Irikura, K.K.; Johnson, R.D., III; Hudgens, J.W., Electronic spectrum of the trichlorosilyl radical, J. Phys. Chem., 1992, 96, 11, 4306, https://doi.org/10.1021/j100190a038 . [all data]

Jacox and Milligan, 1968
Jacox, M.E.; Milligan, D.E., Matrix-Isolation Study of the Vacuum-Ultraviolet Photolysis of Trichlorosilane. The Infrared Spectrum of the Free Radical SiCl3, J. Chem. Phys., 1968, 49, 7, 3130, https://doi.org/10.1063/1.1670560 . [all data]

Miller and Andrews, 1981
Miller, J.H.; Andrews, L., Matrix spectroscopy of the argon resonance photolysis products of group IV chlorides, J. Mol. Struct., 1981, 77, 1-2, 65, https://doi.org/10.1016/0022-2860(81)85267-2 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Leray and Roncin, 1965
Leray, N.; Roncin, J., Hyperfine Interaction of the Chlorine Nucleus in a Solid Matrix, J. Chem. Phys., 1965, 42, 2, 800, https://doi.org/10.1063/1.1696018 . [all data]

Notes

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