Scandium,tris(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-o,o')-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
2.78 ± 0.13IMRBSharpe, Eyler, et al., 1990EA given is actually -ΔGea(350 K). Between fluoranil, Cr(CF3COCHCOCF3)3; B

Ionization energy determinations

IE (eV) Method Reference Comment
9.43 ± 0.05EIWestmore, Reimer, et al., 1981LLK
9.6 ± 0.2PEWestmore, Reimer, et al., 1981LLK
10.13 ± 0.07PEEvans, Hamnett, et al., 1972Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sharpe, Eyler, et al., 1990
Sharpe, P.; Eyler, J.R.; Richardson, D.E., Free Energies of Electron Attachment to Tris(acetylacetonate) and Tris(hexafluoroacetylacetonate) Transition-Metal Complexes in the Gas Phase: Experimental Results and Ligand Field Analysis, Inorg. Chem., 1990, 29, 15, 2779, https://doi.org/10.1021/ic00340a014 . [all data]

Westmore, Reimer, et al., 1981
Westmore, J.B.; Reimer, M.L.J.; Reichert, C., Ionization energies of metal chelates. Acetylacetonates, trifluoroacetylacetonates, and hexafluoroacetylacetonates of trivalent metals of the first transition series, Can. J. Chem., 1981, 59, 1797. [all data]

Evans, Hamnett, et al., 1972
Evans, S.; Hamnett, A.; Orchard, A.F.; Lloyd, D.R., Study of the metal-oxygen bond in simple tris-chelate complexes by He(I) photoelectron spectroscopy, Faraday Discuss. Chem. Soc., 1972, 54, 227. [all data]


Notes

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