Chlorine anion
- Formula: Cl-
- Molecular weight: 35.454
- IUPAC Standard InChIKey: VEXZGXHMUGYJMC-UHFFFAOYSA-M
- CAS Registry Number: 16887-00-6
- Chemical structure:
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 301 to 314
+ C3H9ClGe = C3H9Cl2Ge-
By formula: Cl- + C3H9ClGe = C3H9Cl2Ge-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 92.9 ± 5.9 | kJ/mol | CIDT | Hao, Kaspar, et al., 2005 | gas phase |
+ = Cl5Sn-
By formula: Cl- + Cl4Sn = Cl5Sn-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 235. ± 7.9 | kJ/mol | CIDT | Hao, Kaspar, et al., 2005 | gas phase |
+ = Cl3OS-
By formula: Cl- + Cl2OS = Cl3OS-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 85.4 ± 7.5 | kJ/mol | CIDT | Bachrach, Hayes, et al., 2001 | gas phase |
+ = C3H9Cl2Si-
By formula: Cl- + C3H9ClSi = C3H9Cl2Si-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 59.8 ± 5.9 | kJ/mol | CIDT | Hao, Kaspar, et al., 2005 | gas phase |
+ = Cl3S-
By formula: Cl- + Cl2S = Cl3S-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 84.9 ± 7.9 | kJ/mol | CIDT | Gailbreath, Pommerening, et al., 2000 | gas phase |
By formula: Cl- + Cl3Sb = Cl4Sb-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 160. ± 7.9 | kJ/mol | CIDT | Walker, Check, et al., 2002 | gas phase |
+ = Cl4P-
By formula: Cl- + Cl3P = Cl4P-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 90.0 ± 7.1 | kJ/mol | CIDT | Walker, Check, et al., 2002 | gas phase |
+ = AsCl4-
By formula: Cl- + AsCl3 = AsCl4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 115. ± 7.1 | kJ/mol | CIDT | Walker, Check, et al., 2002 | gas phase |
By formula: Cl- + BiCl3 = BiCl4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 153. ± 15. | kJ/mol | CIDT | Walker, Check, et al., 2002 | gas phase |
= C8H8Cl-
By formula: Cl- = C8H8Cl-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 84.1 ± 6.7 | kJ/mol | CIDT | Hammad and Wenthold, 2000 | gas phase |
= C4HClF9-
By formula: Cl- = C4HClF9-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 64.9 ± 1.3 | kJ/mol | IMRE | Guerrero, Herrero, et al., 2009 | gas phase |
+ = Cl3OSe-
By formula: Cl- + Cl2OSe = Cl3OSe-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 149.8 | kJ/mol | N/A | Lobring, Hao, et al., 2003 | gas phase |
+ = Cl2F2P-
By formula: Cl- + ClF2P = Cl2F2P-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 98.99 | kJ/mol | N/A | Check, Lobring, et al., 2003 | gas phase |
= ClN2O-
By formula: Cl- = ClN2O-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 18.8 ± 0.42 | kJ/mol | N/A | Boesl, Distelrath, et al., 2008 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hao, Kaspar, et al., 2005
Hao, C.T.; Kaspar, J.D.; Check, C.E.; Lobring, K.C.; Gilbert, T.M.; Sunderlin, L.S.,
Effect of substituents on the strength of A-Cl- (A = Si, Ge, and Sn) bonds in hypervalent systems: ACl(5)(-), ACl(4)F(-), and A(CH3)(3)Cl-2(-),
J. Phys. Chem. A, 2005, 109, 9, 2026-2034, https://doi.org/10.1021/jp040743x
. [all data]
Bachrach, Hayes, et al., 2001
Bachrach, S.M.; Hayes, J.M.; Check, C.E.; Sunderlin, L.S.,
Potential energy surface of SOCl3-,
J. Phys. Chem. A, 2001, 105, 41, 9595-9597, https://doi.org/10.1021/jp012412f
. [all data]
Gailbreath, Pommerening, et al., 2000
Gailbreath, B.D.; Pommerening, C.A.; Bachrach, S.M.; Sunderlin, L.S.,
Potential Energy Surface of SCl3-,
J. Phys. Chem., 2000, 104, 13, 2958, https://doi.org/10.1021/jp993671w
. [all data]
Walker, Check, et al., 2002
Walker, B.W.; Check, C.E.; Lobring, K.C.; Pommerening, C.A.; Sunderlin, L.S.,
The Thermochemistry of Group 15 Tetrachloride Anions,
J. Am. Soc. Mass Spectrom., 2002, 13, 5, 469, https://doi.org/10.1016/S1044-0305(02)00369-0
. [all data]
Hammad and Wenthold, 2000
Hammad, L.A.; Wenthold, P.G.,
Synthesis, characterization, and reactivity of the m-xylylene anion in the gas phase. The enthalpy of formation of m-xylylene,
J. Am. Chem. Soc., 2000, 122, 45, 11203-11211, https://doi.org/10.1021/ja002138n
. [all data]
Guerrero, Herrero, et al., 2009
Guerrero, A.; Herrero, R.; Davalos, J.Z.; Koppel, I.; Abboud, J.L.M.; Chana, A.; Koppel, I.A.,
Hydrogen-Bonding Interactions of (CF3)(3)CH and (CF3)(3)C- in the Gas Phase. An Experimental (FT-ICR) and Computational Study,
J. Phys. Chem. A, 2009, 113, 23, 6422-6429, https://doi.org/10.1021/jp811057m
. [all data]
Lobring, Hao, et al., 2003
Lobring, K.C.; Hao, C.T.; Forbes, J.K.; Ivanov, M.R.J.; Bachrach, S.M.; Sunderlin, L.S.,
Bond strengths in ChCl(3)(-) and ChOCl(3)(-) (Ch = S, Se, Te): Experiment and theory,
J. Phys. Chem. A, 2003, 107, 50, 11153-11160, https://doi.org/10.1021/jp030388v
. [all data]
Check, Lobring, et al., 2003
Check, C.E.; Lobring, K.C.; Keating, P.R.; Gilbert, T.M.; Sunderlin, L.S.,
Effect of substituents on the strength of hypervalent phosphorus-halogen bonds,
J. Phys. Chem. A, 2003, 107, 42, 8961-8967, https://doi.org/10.1021/jp030287x
. [all data]
Boesl, Distelrath, et al., 2008
Boesl, U.; Distelrath, V.; Selzle, H.,
The weakly-bound complex Cl center dot N2O studied by high resolution photodetachment photoelectron spectroscopy,
Phys. Chem. Chem. Phys., 2008, 10, 41, 6252-6257, https://doi.org/10.1039/b807992g
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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