Chlorine anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Reactions 301 to 314

Chlorine anion + C3H9ClGe = C3H9Cl2Ge-

By formula: Cl- + C3H9ClGe = C3H9Cl2Ge-

Quantity Value Units Method Reference Comment
Δr92.9 ± 5.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase

Chlorine anion + Tin(IV) chloride = Cl5Sn-

By formula: Cl- + Cl4Sn = Cl5Sn-

Quantity Value Units Method Reference Comment
Δr235. ± 7.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase

Chlorine anion + Thionyl chloride = Cl3OS-

By formula: Cl- + Cl2OS = Cl3OS-

Quantity Value Units Method Reference Comment
Δr85.4 ± 7.5kJ/molCIDTBachrach, Hayes, et al., 2001gas phase

Chlorine anion + Silane, chlorotrimethyl- = C3H9Cl2Si-

By formula: Cl- + C3H9ClSi = C3H9Cl2Si-

Quantity Value Units Method Reference Comment
Δr59.8 ± 5.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase

Chlorine anion + Sulfur dichloride = Cl3S-

By formula: Cl- + Cl2S = Cl3S-

Quantity Value Units Method Reference Comment
Δr84.9 ± 7.9kJ/molCIDTGailbreath, Pommerening, et al., 2000gas phase

Chlorine anion + Cl3Sb = Cl4Sb-

By formula: Cl- + Cl3Sb = Cl4Sb-

Quantity Value Units Method Reference Comment
Δr160. ± 7.9kJ/molCIDTWalker, Check, et al., 2002gas phase

Chlorine anion + Phosphorus trichloride = Cl4P-

By formula: Cl- + Cl3P = Cl4P-

Quantity Value Units Method Reference Comment
Δr90.0 ± 7.1kJ/molCIDTWalker, Check, et al., 2002gas phase

Chlorine anion + Arsenic trichloride = AsCl4-

By formula: Cl- + AsCl3 = AsCl4-

Quantity Value Units Method Reference Comment
Δr115. ± 7.1kJ/molCIDTWalker, Check, et al., 2002gas phase

Chlorine anion + BiCl3 = BiCl4-

By formula: Cl- + BiCl3 = BiCl4-

Quantity Value Units Method Reference Comment
Δr153. ± 15.kJ/molCIDTWalker, Check, et al., 2002gas phase

Chlorine anion = C8H8Cl-

By formula: Cl- = C8H8Cl-

Quantity Value Units Method Reference Comment
Δr84.1 ± 6.7kJ/molCIDTHammad and Wenthold, 2000gas phase

Chlorine anion = C4HClF9-

By formula: Cl- = C4HClF9-

Quantity Value Units Method Reference Comment
Δr64.9 ± 1.3kJ/molIMREGuerrero, Herrero, et al., 2009gas phase

Chlorine anion + seleninyl dichloride = Cl3OSe-

By formula: Cl- + Cl2OSe = Cl3OSe-

Quantity Value Units Method Reference Comment
Δr149.8kJ/molN/ALobring, Hao, et al., 2003gas phase

Chlorine anion + Phosphorus difluoride monochloride = Cl2F2P-

By formula: Cl- + ClF2P = Cl2F2P-

Quantity Value Units Method Reference Comment
Δr98.99kJ/molN/ACheck, Lobring, et al., 2003gas phase

Chlorine anion = ClN2O-

By formula: Cl- = ClN2O-

Quantity Value Units Method Reference Comment
Δr18.8 ± 0.42kJ/molN/ABoesl, Distelrath, et al., 2008gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hao, Kaspar, et al., 2005
Hao, C.T.; Kaspar, J.D.; Check, C.E.; Lobring, K.C.; Gilbert, T.M.; Sunderlin, L.S., Effect of substituents on the strength of A-Cl- (A = Si, Ge, and Sn) bonds in hypervalent systems: ACl(5)(-), ACl(4)F(-), and A(CH3)(3)Cl-2(-), J. Phys. Chem. A, 2005, 109, 9, 2026-2034, https://doi.org/10.1021/jp040743x . [all data]

Bachrach, Hayes, et al., 2001
Bachrach, S.M.; Hayes, J.M.; Check, C.E.; Sunderlin, L.S., Potential energy surface of SOCl3-, J. Phys. Chem. A, 2001, 105, 41, 9595-9597, https://doi.org/10.1021/jp012412f . [all data]

Gailbreath, Pommerening, et al., 2000
Gailbreath, B.D.; Pommerening, C.A.; Bachrach, S.M.; Sunderlin, L.S., Potential Energy Surface of SCl3-, J. Phys. Chem., 2000, 104, 13, 2958, https://doi.org/10.1021/jp993671w . [all data]

Walker, Check, et al., 2002
Walker, B.W.; Check, C.E.; Lobring, K.C.; Pommerening, C.A.; Sunderlin, L.S., The Thermochemistry of Group 15 Tetrachloride Anions, J. Am. Soc. Mass Spectrom., 2002, 13, 5, 469, https://doi.org/10.1016/S1044-0305(02)00369-0 . [all data]

Hammad and Wenthold, 2000
Hammad, L.A.; Wenthold, P.G., Synthesis, characterization, and reactivity of the m-xylylene anion in the gas phase. The enthalpy of formation of m-xylylene, J. Am. Chem. Soc., 2000, 122, 45, 11203-11211, https://doi.org/10.1021/ja002138n . [all data]

Guerrero, Herrero, et al., 2009
Guerrero, A.; Herrero, R.; Davalos, J.Z.; Koppel, I.; Abboud, J.L.M.; Chana, A.; Koppel, I.A., Hydrogen-Bonding Interactions of (CF3)(3)CH and (CF3)(3)C- in the Gas Phase. An Experimental (FT-ICR) and Computational Study, J. Phys. Chem. A, 2009, 113, 23, 6422-6429, https://doi.org/10.1021/jp811057m . [all data]

Lobring, Hao, et al., 2003
Lobring, K.C.; Hao, C.T.; Forbes, J.K.; Ivanov, M.R.J.; Bachrach, S.M.; Sunderlin, L.S., Bond strengths in ChCl(3)(-) and ChOCl(3)(-) (Ch = S, Se, Te): Experiment and theory, J. Phys. Chem. A, 2003, 107, 50, 11153-11160, https://doi.org/10.1021/jp030388v . [all data]

Check, Lobring, et al., 2003
Check, C.E.; Lobring, K.C.; Keating, P.R.; Gilbert, T.M.; Sunderlin, L.S., Effect of substituents on the strength of hypervalent phosphorus-halogen bonds, J. Phys. Chem. A, 2003, 107, 42, 8961-8967, https://doi.org/10.1021/jp030287x . [all data]

Boesl, Distelrath, et al., 2008
Boesl, U.; Distelrath, V.; Selzle, H., The weakly-bound complex Cl center dot N2O studied by high resolution photodetachment photoelectron spectroscopy, Phys. Chem. Chem. Phys., 2008, 10, 41, 6252-6257, https://doi.org/10.1039/b807992g . [all data]


Notes

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