Reaction data
+ 
= ( • )
- Reaction by formula: Cl- + C4H10O = (Cl- • C4H10O)
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Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
| ΔrH° (kcal/mol) | Method | Reference | Comment |
|---|---|---|---|
| 20.20 ± 0.40 | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
| 19.50 ± 0.20 | TDAs | Sieck, 1985 | gas phase; B,M |
| 19.8 ± 1.0 | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
| 18.1 ± 2.0 | IMRE | Larson and McMahon, 1984 | gas phase; B,M |
| 19.2 | PHPMS | Kebarle, 1977 | gas phase; M |
| 14.2 ± 2.0 | TDAs | Yamdagni and Kebarle, 1971 | gas phase; B,M |
References
Go To: Top, Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bogdanov, Peschke, et al., 1999
Bogdanov, B.; Peschke, M.; Tonner, D.S.; Szulejko, J.E.; McMahon, T.B.,
Stepwise solvation of halides by alcohol molecules in the gas phase,
Int. J. Mass Spectrom., 1999, 187, 707-725, https://doi.org/10.1016/S1387-3806(98)14180-5
. [all data]
Sieck, 1985
Sieck, L.W.,
Thermochemistry of Solvation of NO2- and C6H5NO2- by Polar Molecules in the Vapor Phase. Comparison with Cl- and Variation with Ligand Structure.,
J. Phys. Chem., 1985, 89, 25, 5552, https://doi.org/10.1021/j100271a049
. [all data]
Hiraoka and Mizuse, 1987
Hiraoka, K.; Mizuse, S.,
Gas-Phase Solvation of Cl- with H2O, CH3OH, C2H4OH, i-C3H7OH, n-C3H7OH, and t-C4H9OH,
Chem. Phys., 1987, 118, 3, 457, https://doi.org/10.1016/0301-0104(87)85078-4
. [all data]
Larson and McMahon, 1984
Larson, J.W.; McMahon, T.B.,
Hydrogen bonding in gas phase anions. An experimental investigation of the interaction between chloride ion and bronsted acids from ICR chloride exchange equilibria,
J. Am. Chem. Soc., 1984, 106, 517. [all data]
Kebarle, 1977
Kebarle, P.,
Ion Thermochemistry and Solvation from Gas Phase Ion Equilibria,
Ann. Rev. Phys. Chem., 1977, 28, 1, 445, https://doi.org/10.1146/annurev.pc.28.100177.002305
. [all data]
Yamdagni and Kebarle, 1971
Yamdagni, R.; Kebarle, P.,
Hydrogen bonding energies to negative ions from gas phase measurements of ionic equilibria,
J. Am. Chem. Soc., 1971, 93, 7139. [all data]
Notes
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- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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