Deuterium

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to D+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
0.754579 ± 0.000087LPESLykke, Murray, et al., 1991Reported: 6086.2±0.6 cm-1. Acid taken as HD -> H+ + D-; B
0.754579 ± 0.000044LPESLykke, Murray, et al., 1991Acid: D2 -> D- + D+. BDE: 105.98 Gurvich, Veyts, et al.. ΔSacid 22.9; B

Ionization energy determinations

IE (eV) Method Reference Comment
13.603SKelly, 1987LBLHLM
13.602SGarcia and Mack, 1965RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lykke, Murray, et al., 1991
Lykke, K.R.; Murray, K.K.; Lineberger, W.C., Threshold Photodetachment of H-, Phys. Rev. A, 1991, 43, 11, 6104, https://doi.org/10.1103/PhysRevA.43.6104 . [all data]

Gurvich, Veyts, et al.
Gurvich, L.V.; Veyts, I.V.; Alcock, C.B., Hemisphere Publishing, NY, 1989, V. 1 2, Thermodynamic Properties of Individual Substances, 4th Ed. [all data]

Kelly, 1987
Kelly, R.L., Atomic and ionic spectrum lines of hydrogen through kryton, J. Phys. Chem. Ref. Data, 1987, 16. [all data]

Garcia and Mack, 1965
Garcia, J.D.; Mack, J.E., Energy level and line tables for one-electron atomic spectra, J. Opt. Soc. Am., 1965, 55, 654. [all data]


Notes

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