HS anion

• Formula: HS^-
• Molecular weight: 33.073
• CAS Registry Number: 15035-72-0
• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Ion clustering data
  • Constants of diatomic molecules
  • References
  • Notes
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

HS^- +  =

By formula: HS^- + H⁺ = H₂S

(HS^- • 4294967295) +  = HS^-

By formula: (HS^- • 4294967295S) + S = HS^-

HS^- +  = (HS^- • )

By formula: HS^- + C₂H₆O = (HS^- • C₂H₆O)

HS^- +  = (HS^- • )

By formula: HS^- + H₂O = (HS^- • H₂O)

Bond type: Hydrogen bond (negative ion to hydride)

(HS^- • 2) +  = (HS^- • 3)

By formula: (HS^- • 2H₂O) + H₂O = (HS^- • 3H₂O)

Bond type: Hydrogen bond (negative ion to hydride)

(HS^- • ) +  = (HS^- • 2)

By formula: (HS^- • H₂O) + H₂O = (HS^- • 2H₂O)

Bond type: Hydrogen bond (negative ion to hydride)

HS^- +  = (HS^- • )

By formula: HS^- + CHN = (HS^- • CHN)

HS^- +  = (HS^- • )

By formula: HS^- + C₄H₁₀O = (HS^- • C₄H₁₀O)

HS^- +  = (HS^- • )

By formula: HS^- + C₂H₃F₃O = (HS^- • C₂H₃F₃O)

HS^- +  = (HS^- • )

By formula: HS^- + H₂S = (HS^- • H₂S)

HS^- +  = (HS^- • )

By formula: HS^- + C₄H₅N = (HS^- • C₄H₅N)

HS^- +  = (HS^- • )

By formula: HS^- + C₆H₁₁NO₃ = (HS^- • C₆H₁₁NO₃)

HS^- +  = (HS^- • )

By formula: HS^- + CH₄O = (HS^- • CH₄O)

HS^- +  = (HS^- • )

By formula: HS^- + C₆H₁₁NO₃ = (HS^- • C₆H₁₁NO₃)

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

HS^- +  =

By formula: HS^- + H⁺ = H₂S

Ion clustering data

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Constants of diatomic molecules, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

HS^- +  = (HS^- • )

By formula: HS^- + CHN = (HS^- • CHN)

HS^- +  = (HS^- • )

By formula: HS^- + CH₄O = (HS^- • CH₄O)

HS^- +  = (HS^- • )

By formula: HS^- + C₂H₃F₃O = (HS^- • C₂H₃F₃O)

HS^- +  = (HS^- • )

By formula: HS^- + C₂H₆O = (HS^- • C₂H₆O)

HS^- +  = (HS^- • )

By formula: HS^- + C₄H₅N = (HS^- • C₄H₅N)

HS^- +  = (HS^- • )

By formula: HS^- + C₄H₁₀O = (HS^- • C₄H₁₀O)

HS^- +  = (HS^- • )

By formula: HS^- + C₆H₁₁NO₃ = (HS^- • C₆H₁₁NO₃)

HS^- +  = (HS^- • )

By formula: HS^- + C₆H₁₁NO₃ = (HS^- • C₆H₁₁NO₃)

HS^- +  = (HS^- • )

By formula: HS^- + H₂O = (HS^- • H₂O)

Bond type: Hydrogen bond (negative ion to hydride)

(HS^- • ) +  = (HS^- • 2)

By formula: (HS^- • H₂O) + H₂O = (HS^- • 2H₂O)

Bond type: Hydrogen bond (negative ion to hydride)

(HS^- • 2) +  = (HS^- • 3)

By formula: (HS^- • 2H₂O) + H₂O = (HS^- • 3H₂O)

Bond type: Hydrogen bond (negative ion to hydride)

HS^- +  = (HS^- • )

By formula: HS^- + H₂S = (HS^- • H₂S)

(HS^- • 4294967295) +  = HS^-

By formula: (HS^- • 4294967295S) + S = HS^-

Constants of diatomic molecules

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through July, 1977

Notes

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rempala and Ervin, 2000
Rempala, K.; Ervin, K.M., Collisional activation of the Endoergic Hydrogen Atom Transfer Reaction S-(2P) + H2 - SH- + H, J. Chem. Phys., 2000, 112, 10, 4579, https://doi.org/10.1063/1.481016 . [all data]

Bartmess, Scott, et al., 1979
Bartmess, J.E.; Scott, J.A.; McIver, R.T., Jr., The gas phase acidity scale from methanol to phenol, J. Am. Chem. Soc., 1979, 101, 6047. [all data]

Shiell, Hu, et al., 1900
Shiell, R.C.; Hu, X.K.; Hu, Q.J.; Hepburn, J.W., A determination of the bond dissociation energy (D-0(H-SH)): Threshold ion-pair production spectroscopy (TIPPS) of a triatomic molecule, J. Phys. Chem. A, 1900, 104, 19, 4339-4342, https://doi.org/10.1021/jp000025k . [all data]

Gurvich, Veyts, et al.
Gurvich, L.V.; Veyts, I.V.; Alcock, C.B., Hemisphere Publishing, NY, 1989, V. 1 2, Thermodynamic Properties of Individual Substances, 4th Ed. [all data]

Breyer, Frey, et al., 1981
Breyer, F.; Frey, P.; Hotop, H., High Resolution Photoelectron Spectrometry of Negative Ions: Rotational Transitions in Laser-Photodetachment of OH-, SH-, and SD-, Z. Phys. A, 1981, 300, 1, 7, https://doi.org/10.1007/BF01412609 . [all data]

Cumming and Kebarle, 1978
Cumming, J.B.; Kebarle, P., Summary of gas phase measurements involving acids AH. Entropy changes in proton transfer reactions involving negative ions. Bond dissociation energies D(A-H) and electron affinities EA(A), Can. J. Chem., 1978, 56, 1. [all data]

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]

Chaibi, Delsart, et al., 2006
Chaibi, W.; Delsart, C.; Drag, C.; Blondel, C., High precision measurement of the (SH)-S-32 electron affinity by laser detachment microscopy, J. Molec. Spectros., 2006, 239, 1, 11-15, https://doi.org/10.1016/j.jms.2006.05.012 . [all data]

Sieck and Meot-ner, 1989
Sieck, L.W.; Meot-ner, M., Ionic Hydrogen Bond and Ion Solvation. 8. RS-..HOR Bond Strengths. Correlation with Acidities., J. Phys. Chem., 1989, 93, 4, 1586, https://doi.org/10.1021/j100341a079 . [all data]

Meot-ner, 1988
Meot-ner, M., Ionic Hydrogen Bond and Ion Solvation. ₆. Interaction Energies of the Acetate Ion with Organic Molecules. Comparison of CH₃COO^- with Cl^-, CN^-, and SH^-, J. Am. Chem. Soc., 1988, 110, 12, 3854, https://doi.org/10.1021/ja00220a022 . [all data]

Steiner, 1968
Steiner, B., Photodetachment of Electrons From SH^-, J. Chem. Phys., 1968, 49, 11, 5097, https://doi.org/10.1063/1.1670004 . [all data]

Cade, 1967
Cade, P.E., Hartree-Fock wavefunctions, potential curves, and molecular properties for OH-(¹Σ⁺) and SH-(¹Σ⁺), J. Chem. Phys., 1967, 47, 2390. [all data]

Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Constants of diatomic molecules, References

• Symbols used in this document:
  

  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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