Rhenium, pentacarbonyl(pentacarbonylmanganese)-, (Mn-Re)

Formula: C₁₀MnO₁₀Re
Molecular weight: 521.246
IUPAC Standard InChI: InChI=1S/10CO.Mn.Re/c10*1-2;;
IUPAC Standard InChIKey: JHLLDJQETNNXIR-UHFFFAOYSA-N
CAS Registry Number: 14693-30-2
Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript.
Other names: Rhenium, pentacarbonyl(pentacarbonylmanganio)-; Decacarbonylmanganeserhenium; Manganese rhenium carbonyl (MnRe(CO)10); Manganese, decacarbonylrhenium-; MnRe(CO)10
Permanent link for this species. Use this link for bookmarking this species for future reference.
Information on this page:
Other data available:
- Phase change data
- Mass spectrum (electron ionization)
Options:
- Switch to calorie-based units

Gas phase ion energetics data

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV)	Method	Reference	Comment
8.22 ± 0.01	EI	Michels and Svec, 1981	LLK
8.14 ± 0.01	EI	Junk and Svec, 1970	RDSH

Appearance energy determinations

Ion	AE (eV)	Other Products	Method	Reference	Comment
CMnO⁺	19.05	?	EI	Svec and Junk, 1967	RDSH
CMnORe⁺	23.00	9CO	EI	Svec and Junk, 1967	RDSH
C₂MnO₂Re⁺	19.75	8CO	EI	Svec and Junk, 1967	RDSH
C₃MnO₃Re⁺	16.94	7CO	EI	Svec and Junk, 1967	RDSH
C₄MnO₄Re⁺	14.65	6CO	EI	Svec and Junk, 1967	RDSH
C₅MnO₅⁺	10.50	?	EI	Junk and Svec, 1970	RDSH
C₅MnO₅Re⁺	12.12	5CO	EI	Svec and Junk, 1967	RDSH
C₅O₅Re⁺	10.80	?	EI	Svec and Junk, 1967	RDSH
C₆O₆Re⁺	9.36	?	EI	Svec and Junk, 1967	RDSH
Mn⁺	25.67	?	EI	Svec and Junk, 1967	RDSH
MnRe⁺	25.98	10CO	EI	Svec and Junk, 1967	RDSH
Re⁺	30.93	?	EI	Svec and Junk, 1967	RDSH

References

Go To: Top, Gas phase ion energetics data, Notes

Michels and Svec, 1981
Michels, G.D.; Svec, H.J., Characterization of MnTc(CO)₁₀ and TcRe(CO)₁₀, Inorg. Chem., 1981, 20, 3445. [all data]

Junk and Svec, 1970
Junk, G.A.; Svec, H.J., The mass spectra, ionization potentials, and bond energies of the group VIIA decacarbonyls, J. Chem. Soc. A, 1970, 2102. [all data]

Svec and Junk, 1967
Svec, H.J.; Junk, G.A., Energetics of the ionization and dissociation of Mn₂(CO)₁₀, Re₂(CO)₁₀, and ReMn(CO)₁₀, J. Am. Chem. Soc., 1967, 89, 2836. [all data]

Notes

Go To: Top, Gas phase ion energetics data, References

Symbols used in this document:

AE Appearance energy
Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
Customer support for NIST Standard Reference Data products.