Iron ion (1+)
- Formula: Fe+
- Molecular weight: 55.844
- IUPAC Standard InChIKey: WZGNVVUXVXNNOX-UHFFFAOYSA-N
- CAS Registry Number: 14067-02-8
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Iron cation
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Gas phase thermochemistry data
- Reaction thermochemistry data: reactions 1 to 50
- Ion clustering data
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 51 to 79
By formula: (Fe+ • 3H3N) + H3N = (Fe+ • 4H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 10.0 ± 1.7 | kcal/mol | CIDT | Walter and Armentrout, 1998 | RCD |
By formula: (Fe+ • 2N2) + N2 = (Fe+ • 3N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 10.8 ± 0.7 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: (Fe+ • 3N2) + N2 = (Fe+ • 4N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12.9 ± 1.0 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: (Fe+ • 4N2) + N2 = (Fe+ • 5N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14.8 ± 1.0 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Fe+ + C2H6Si = (Fe+ • C2H6Si)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 68.5 ± 8.5 | kcal/mol | ICR | Jacobson and Bakhtiar, 1993 | gas phase; M |
By formula: Fe+ + CH4Si = (Fe+ • CH4Si)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 62.5 ± 7.5 | kcal/mol | ICR | Jacobson and Bakhtiar, 1993 | gas phase; M |
By formula: (Fe+ • N2) + N2 = (Fe+ • 2N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 19.8 ± 2.2 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Fe+ + H2Si = (Fe+ • H2Si)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 67. ± 12. | kcal/mol | ICR | Jacobson and Bakhtiar, 1993 | gas phase; M |
By formula: Fe+ + C2H6Si = (Fe+ • C2H6Si)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 63. ± 8. | kcal/mol | ICR | Jacobson and Bakhtiar, 1993 | gas phase; M |
By formula: Fe+ + CH4Si = (Fe+ • CH4Si)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 67. ± 11. | kcal/mol | ICR | Jacobson and Bakhtiar, 1993 | gas phase; M |
By formula: Fe+ + C3H8Si = (Fe+ • C3H8Si)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 64. ± 9. | kcal/mol | ICR | Jacobson and Bakhtiar, 1993 | gas phase; M |
By formula: (Fe+ • 2CH2O) + CH2O = (Fe+ • 3CH2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 18.2 ± 1.0 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: (Fe+ • 3CH2O) + CH2O = (Fe+ • 4CH2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12.0 ± 1.7 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: (Fe+ • C2H4) + C2H4 = (Fe+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 36.1 ± 3.6 | kcal/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
By formula: (Fe+ • CH2O) + CH2O = (Fe+ • 2CH2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 39.2 ± 1.0 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: (Fe+ • CS2) + CS2 = (Fe+ • 2CS2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 44.9 ± 1.4 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: (Fe+ • C4H5N) + C4H5N = (Fe+ • 2C4H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 41.6 | kcal/mol | RAK | Gapeev and Yang, 2000 | RCD |
By formula: Fe+ + C5H5N = (Fe+ • C5H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 53.4 ± 2.2 | kcal/mol | CIDT | Rodgers, Stanley, et al., 2000 | RCD |
By formula: Fe+ + Xe = (Fe+ • Xe)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 10.0 ± 1.4 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Fe+ + N2 = (Fe+ • N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12.9 ± 1.4 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Fe+ + C4H4N2 = (Fe+ • C4H4N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 47.5 ± 1.9 | kcal/mol | CIDT | Amunugama and Rodgers, 2001 | RCD |
By formula: Fe+ + Kr = (Fe+ • Kr)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.2 ± 1.7 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Fe+ + Ar = (Fe+ • Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.6 ± 1.9 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Fe+ + CO2 = (Fe+ • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14.3 ± 1.0 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Fe+ + C2H2 = (Fe+ • C2H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 36.1 ± 1.9 | kcal/mol | IRMPD | Surya, Ranatunga, et al., 1997 | RCD |
By formula: Fe+ + C5H5N5 = (Fe+ • C5H5N5)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 62.0 ± 2.1 | kcal/mol | CIDT | Rodgers and Armentrout, 2002 | RCD |
By formula: Fe+ + CH2O = (Fe+ • CH2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 33.0 ± 1.7 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Fe+ + CS2 = (Fe+ • CS2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 39.7 ± 1.2 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Fe+ + C4H5N = (Fe+ • C4H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 54.0 | kcal/mol | RAK | Gapeev and Yang, 2000 | RCD |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B.,
Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD,
J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c
. [all data]
Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B.,
Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation,
Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X
. [all data]
Jacobson and Bakhtiar, 1993
Jacobson, D.B.; Bakhtiar, R.,
Generation, Characterization and Properties of Iron-Silylene and Iron-Sylene Cationic Complexes in the Gas Phase,
J. Am. Chem. Soc., 1993, 115, 23, 10830, https://doi.org/10.1021/ja00076a046
. [all data]
Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B.,
Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes,
J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z
. [all data]
Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N.,
Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results,
J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d
. [all data]
Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R.,
Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory,
J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923
. [all data]
Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T.,
Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory,
J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i
. [all data]
Surya, Ranatunga, et al., 1997
Surya, P.I.; Ranatunga, D.R.A.; Freiser, B.S.,
Infrared Multiphoton Dissociation of MC4H6+ [M=Fe, Co or Ni: C4H6=1,3-butadiene or (C2H2)(C2H4),
J. Am. Chem. Soc., 1997, 119, 14, 3351, https://doi.org/10.1021/ja963200c
. [all data]
Rodgers and Armentrout, 2002
Rodgers, M.T.; Armentrout, P.B.,
Influence of d orbital occupation on the binding of metal ions to adenine,
J. Am. Chem. Soc., 2002, 124, 11, 2678, https://doi.org/10.1021/ja011278+
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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