Dimethyldithiocarbamic acid,copper salt
- Formula: C6H12CuN2S4
- Molecular weight: 303.979
- IUPAC Standard InChI: InChI=1S/2C3H7NS2.Cu/c2*1-4(2)3(5)6;/h2*1-2H3,(H,5,6);/q;;+2/p-2
- IUPAC Standard InChIKey: ZOUQIAGHKFLHIA-UHFFFAOYSA-L
- CAS Registry Number: 137-29-1
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Copper, bis(dimethylcarbamodithioato-S,S')-, (SP-4-1)-; Carbamic acid, dimethyldithio-, copper(ii) salt; Compound-4018; Copper, bis(dimethyldithiocarbamato)-; Copper(II) dimethyldithiocarbamate; Cumate; Wolfen; Akrochem Cu.D.D; Bis(dimethylcarbamodithioato-S,S') copper; Copper dimethyl dithiocarbamate; Perkacit CDMC; copper bis(dimethyldithiocarbamate); bis(dimethyldithiocarbamate)copper
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔsubH° | 156.0 ± 0.3 | kJ/mol | C | Ribeiro da Silva, Reis, et al., 1995 |
Enthalpy of vaporization
| ΔvapH (kJ/mol) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 147.4 | 458. | Dykyj, Svoboda, et al., 1999 | Based on data from 443. - 473. K. |
Enthalpy of sublimation
| ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 147.4 ± 0.8 | 458. | A | Stephenson and Malanowski, 1987 | Based on data from 443. - 473. K. See also Tavlaridis and Neeb, 1978. |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ribeiro da Silva, Reis, et al., 1995
Ribeiro da Silva, M.A.V.; Reis, A.M.M.V.; Faria, R.I.M.C.P.,
Standard enthalpies of formation of crystalline dimethylammoniumdimethyldithiocarbamate and dimethyldithiocarbamate complexes of copper(II) and nickel(II). The mean Cu-S and Ni-S bond-dissociation enthalpies,
J. Chem. Thermodyn., 1995, 27, 1365-1372. [all data]
Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R.,
Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Tavlaridis and Neeb, 1978
Tavlaridis, Athanassios; Neeb, Rolf,
Dialkyldithiocarbamates as reagents for the gas-chromatographic determination of metals,
Z. Anal. Chem., 1978, 293, 3, 211-219, https://doi.org/10.1007/BF00491050
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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