Boron triiodide
- Formula: BI3
- Molecular weight: 391.524
- IUPAC Standard InChI: InChI=1S/BI3/c2-1(3)4
- IUPAC Standard InChIKey: YMEKEHSRPZAOGO-UHFFFAOYSA-N
- CAS Registry Number: 13517-10-7
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: BI3; Borane, triiodo-; Triiodoborane
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 9.25 ± 0.03 | PE | Bassett and Lloyd, 1971 | LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| B+ | 16.6 ± 0.5 | ? | EI | Koski, Kaufman, et al., 1959 | RDSH |
| BI+ | 14.4 ± 0.2 | ? | EI | Koski, Kaufman, et al., 1959 | RDSH |
| BI2+ | 9.7 ± 0.2 | I | EI | Koski, Kaufman, et al., 1959 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bassett and Lloyd, 1971
Bassett, P.J.; Lloyd, D.R.,
Photoelectron spectra of halides. Part II.High-resolution spectra of the boron trihalides,
J. Chem. Soc., 1971, (A), 1551. [all data]
Koski, Kaufman, et al., 1959
Koski, W.S.; Kaufman, J.J.; Pachucki, C.F.,
A mass spectroscopic appearance potential study of some boron trihalides,
J. Am. Chem. Soc., 1959, 81, 1326. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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