thiophenoxide anion
- Formula: C6H5S-
- Molecular weight: 109.169
- IUPAC Standard InChI: InChI=1S/C6H6S/c7-6-4-2-1-3-5-6/h1-5,7H/p-1
- IUPAC Standard InChIKey: RMVRSNDYEFQCLF-UHFFFAOYSA-M
- CAS Registry Number: 13133-62-5
- Chemical structure:
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Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
+
= (
•
)
By formula: C6H5S- + CH4O = (C6H5S- • CH4O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 13.4 | kcal/mol | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.0 | cal/mol*K | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
+
= C7H9OS-
By formula: C6H5S- + CH4O = C7H9OS-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 13.40 ± 0.10 | kcal/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 6.50 ± 0.30 | kcal/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B |
+
= (
•
)
By formula: C6H5S- + C2H3F3O = (C6H5S- • C2H3F3O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 21.0 | kcal/mol | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25.1 | cal/mol*K | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
+
= C8H8F3OS-
By formula: C6H5S- + C2H3F3O = C8H8F3OS-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 21.00 ± 0.20 | kcal/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 13.50 ± 0.60 | kcal/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B |
+
= (
•
)
By formula: C6H5S- + C2H4O2 = (C6H5S- • C2H4O2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 20.3 | kcal/mol | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26.2 | cal/mol*K | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
+
= C8H9O2S-
By formula: C6H5S- + C2H4O2 = C8H9O2S-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 20.30 ± 0.10 | kcal/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 12.50 ± 0.40 | kcal/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B |
+
= C9H11O2S-
By formula: C6H5S- + C3H6O2 = C9H11O2S-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 20.00 ± 0.40 | kcal/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 12.4 ± 1.3 | kcal/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B |
+
= (
•
)
By formula: C6H5S- + C3H6O2 = (C6H5S- • C3H6O2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 20.0 | kcal/mol | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25.6 | cal/mol*K | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
+
= C9H13OS-
By formula: C6H5S- + C3H8O = C9H13OS-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 15.00 ± 0.10 | kcal/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 7.30 ± 0.40 | kcal/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B |
+
= (
•
)
By formula: C6H5S- + C3H8O = (C6H5S- • C3H8O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 15.0 | kcal/mol | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26.0 | cal/mol*K | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
+
= (
•
)
By formula: C6H5S- + C4H10O = (C6H5S- • C4H10O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 14.6 | kcal/mol | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25.0 | cal/mol*K | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
+
= C10H15OS-
By formula: C6H5S- + C4H10O = C10H15OS-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 14.60 ± 0.10 | kcal/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 7.20 ± 0.50 | kcal/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B |
+
= (
•
)
By formula: C6H5S- + H2O = (C6H5S- • H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 11.4 | kcal/mol | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 19.6 | cal/mol*K | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
+
= C6H7OS-
By formula: C6H5S- + H2O = C6H7OS-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 11.40 ± 0.20 | kcal/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 5.60 ± 0.70 | kcal/mol | TDAs | Sieck and Meot-ner, 1989 | gas phase; B |
References
Go To: Top, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Sieck and Meot-ner, 1989
Sieck, L.W.; Meot-ner, M.,
Ionic Hydrogen Bond and Ion Solvation. 8. RS-..HOR Bond Strengths. Correlation with Acidities.,
J. Phys. Chem., 1989, 93, 4, 1586, https://doi.org/10.1021/j100341a079
. [all data]
Notes
Go To: Top, Ion clustering data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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