Sulfur trioxide anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-579.1 ± 9.6kJ/molR-EAGleason, 1987See also Dobrin, Boo, et al., 2000
Δfgas-595.0 ± 7.5kJ/molTDEqRudny, Sidorov, et al., 1985EA is calculated at 298 K.; value altered from reference due to conversion from electron convention to ion convention

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

O3S- + Carbon dioxide = (O3S- • Carbon dioxide)

By formula: O3S- + CO2 = (O3S- • CO2)

Quantity Value Units Method Reference Comment
Δr27.2 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Δr86.6J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr1.3 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B

(O3S- • Sulfur dioxide • Oxygen) + Sulfur dioxide = (O3S- • 2Sulfur dioxide • Oxygen)

By formula: (O3S- • O2S • O2) + O2S = (O3S- • 2O2S • O2)

Quantity Value Units Method Reference Comment
Δr23.8 ± 2.5kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B
Quantity Value Units Method Reference Comment
Δr15. ± 8.8kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B

(O3S- • Oxygen) + Sulfur dioxide = (O3S- • Sulfur dioxide • Oxygen)

By formula: (O3S- • O2) + O2S = (O3S- • O2S • O2)

Quantity Value Units Method Reference Comment
Δr27.2 ± 3.3kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B
Quantity Value Units Method Reference Comment
Δr18. ± 9.2kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B

O3S- + Sulfur dioxide = (O3S- • Sulfur dioxide)

By formula: O3S- + O2S = (O3S- • O2S)

Quantity Value Units Method Reference Comment
Δr55.65 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B
Quantity Value Units Method Reference Comment
Δr31.8 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B

O3S- + Water = (O3S- • Water)

By formula: O3S- + H2O = (O3S- • H2O)

Quantity Value Units Method Reference Comment
Δr23.4 ± 0.84kJ/molIMREMöhler, Reiner, et al., 1992gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
25.296.FAFehsenfeld and Ferguson, 1974gas phase; M

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

O3S- + Carbon dioxide = (O3S- • Carbon dioxide)

By formula: O3S- + CO2 = (O3S- • CO2)

Quantity Value Units Method Reference Comment
Δr27.2 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Δr86.6J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr1.3 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B

O3S- + Water = (O3S- • Water)

By formula: O3S- + H2O = (O3S- • H2O)

Quantity Value Units Method Reference Comment
Δr23.4 ± 0.84kJ/molIMREMöhler, Reiner, et al., 1992gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
25.296.FAFehsenfeld and Ferguson, 1974gas phase; M

O3S- + Sulfur dioxide = (O3S- • Sulfur dioxide)

By formula: O3S- + O2S = (O3S- • O2S)

Quantity Value Units Method Reference Comment
Δr55.65 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B
Quantity Value Units Method Reference Comment
Δr31.8 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B

(O3S- • Sulfur dioxide • Oxygen) + Sulfur dioxide = (O3S- • 2Sulfur dioxide • Oxygen)

By formula: (O3S- • O2S • O2) + O2S = (O3S- • 2O2S • O2)

Quantity Value Units Method Reference Comment
Δr23.8 ± 2.5kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B
Quantity Value Units Method Reference Comment
Δr15. ± 8.8kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B

(O3S- • Oxygen) + Sulfur dioxide = (O3S- • Sulfur dioxide • Oxygen)

By formula: (O3S- • O2) + O2S = (O3S- • O2S • O2)

Quantity Value Units Method Reference Comment
Δr27.2 ± 3.3kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B
Quantity Value Units Method Reference Comment
Δr18. ± 9.2kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gleason, 1987
Gleason, J.F., as cited in 95MIL/VIG, Ph.D. dissertation, Univ. of Colorado,, 1987. [all data]

Dobrin, Boo, et al., 2000
Dobrin, S.; Boo, B.H.; Alconcel, L.S.; Continetti, R.E., Photoelectron spectroscopy of SO3- at 355 and 266 nm, J. Phys. Chem. A, 2000, 104, 46, 10695-10700, https://doi.org/10.1021/jp0025680 . [all data]

Rudny, Sidorov, et al., 1985
Rudny, E.B.; Sidorov, L.N.; Voyk, O.M., Heterolytic Dissociation of Potassium Sulfate in the Gas Phase and Heats of Formation for Trioxosulfate(1-), Tetraoxosulfate(1-), and Potassium Sulfate(KSO4-) Ions, High Temp., 1985, 23, 238. [all data]

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

Vacher, Jorda, et al., 1992
Vacher, J.R.; Jorda, M.; Leduc, E.; Fitaire, M., A Determination of the Stabilities of Negative Ion Clusters in SO2 and SO2-O2 Mixtures, Int. J. Mass Spectrom. Ion Proc., 1992, 114, 3, 149, https://doi.org/10.1016/0168-1176(92)80033-W . [all data]

Möhler, Reiner, et al., 1992
Möhler, O.; Reiner, T.; Arnold, F., The Formation of SO5(-) by Gas Phase Ion-Molecule Reactions, J. Chem. Phys., 1992, 97, 11, 8233, https://doi.org/10.1063/1.463394 . [all data]

Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E., Laboratory studies of negative ion reactions with atmospheric trace constituents, J. Chem. Phys., 1974, 61, 3181. [all data]


Notes

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