Benzophenone
- Formula: C13H10O
- Molecular weight: 182.2179
- IUPAC Standard InChIKey: RWCCWEUUXYIKHB-UHFFFAOYSA-N
- CAS Registry Number: 119-61-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Methanone, diphenyl-; α-Oxodiphenylmethane; α-Oxoditane; Benzene, benzoyl-; Benzoylbenzene; Diphenyl ketone; Diphenylmethanone; Phenyl ketone; Ketone, diphenyl; alpha-Oxodiphenylmethane; alpha-Oxoditane; Adjutan 6016; Kayacure BP; Diphenyl-methanon; NSC 8077; 1-Benzophenone; Cinnarizine M (benzophenone); Cyclizine M (Benzophenone)
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Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.)
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
ΔsubH° (kJ/mol) | Method | Reference | Comment |
---|---|---|---|
93.1 ± 2.1 | GS | Verevkin, 1998 | AC |
84.4 ± 1.1 | C | Sabbah and Laffitte, 1978 | ALS |
84.4 ± 1.1 | C | Sabbah and Laffitte, 1978 | AC |
77.0 ± 2.5 | ME | Arshadi, 1974 | Based on data from 278. to 311. K.; AC |
92. ± 0.83 | C | Sabbah, 1974 | See also Kruif, Miltenburg, et al., 1983.; AC |
94.6 ± 0.8 | TCM | de Kruif and Oonk, 1973 | Based on data from 295. to 304. K.; AC |
93.3 ± 0.3 | V | Morawetz, 1972 | ALS |
93.4 ± 0.3 | C | Morawetz, 1972, 2 | AC |
85.4 | V | Springall and White, 1954 | ALS |
95. ± 2.5 | TE | Neumann and Volker, 1932 | See also Cox and Pilcher, 1970 and Jones, 1960.; AC |
91.2 ± 1.6 | ME | Volmer and Kirchhoff, 1925 | Based on data from 273. to 320. K.; AC |
References
Go To: Top, Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Verevkin, 1998
Verevkin, S.P.,
Thermochemistry of aromatic ketones. Experimental enthalpies of formation and structural effects,
Thermochim. Acta, 1998, 310, 229-235. [all data]
Sabbah and Laffitte, 1978
Sabbah, R.; Laffitte, M.,
Etude thermodynamique de la molecule de benzophenone,
Thermochim. Acta, 1978, 23, 196-198. [all data]
Arshadi, 1974
Arshadi, Mohammed R.,
Determination of heats of sublimation of organic compounds by a mass spectrometric--knudsen effusion method,
J. Chem. Soc., Faraday Trans. 1, 1974, 70, 0, 1569, https://doi.org/10.1039/f19747001569
. [all data]
Sabbah, 1974
Sabbah, R.,
Energetique de Liaison Inter-et Intra-moleculaires C.N.R.S.: Marseille, 1974. [all data]
Kruif, Miltenburg, et al., 1983
Kruif, C.G. de; Miltenburg, J.C. van; Blok, J.G.,
Molar heat capacities and vapour pressures of solid and liquid benzophenone,
The Journal of Chemical Thermodynamics, 1983, 15, 2, 129-136, https://doi.org/10.1016/0021-9614(83)90151-9
. [all data]
de Kruif and Oonk, 1973
de Kruif, C.G.; Oonk, H.A.J.,
The determination of enthalpies of sublimation by means of thermal conductivity manometers,
Chemie Ing. Techn., 1973, 45, 7, 455-461, https://doi.org/10.1002/cite.330450705
. [all data]
Morawetz, 1972
Morawetz, E.,
Enthalpies of vaporization for a number of aromatic compounds,
J. Chem. Thermodyn., 1972, 4, 455. [all data]
Morawetz, 1972, 2
Morawetz, Ernst,
Correlation of sublimation enthalpies at 298.15 K with molecular structure for planar aromatic hydrocarbons,
The Journal of Chemical Thermodynamics, 1972, 4, 3, 461-467, https://doi.org/10.1016/0021-9614(72)90030-4
. [all data]
Springall and White, 1954
Springall, H.D.; White, T.R.,
Heats of combustion and molecular structure. Part II. The mean bond energy term for the carbonyl system in certain ketones,
J. Chem. Soc., 1954, 2765-27. [all data]
Neumann and Volker, 1932
Neumann, K.; Volker, E.,
Z. Phys. Chem. Abt. A, 1932, 161, 33. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press Inc., London, 1970, 643. [all data]
Jones, 1960
Jones, A.H.,
Sublimation Pressure Data for Organic Compounds.,
J. Chem. Eng. Data, 1960, 5, 2, 196-200, https://doi.org/10.1021/je60006a019
. [all data]
Volmer and Kirchhoff, 1925
Volmer, M.; Kirchhoff, P.,
Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1925, 115, 223. [all data]
Notes
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- Symbols used in this document:
ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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