Nitrous oxide

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Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
MS - José A. Martinho Simões
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 51 to 83

(Fluorine anion • 3Nitrous oxide) + Nitrous oxide = (Fluorine anion • 4Nitrous oxide)

By formula: (F- • 3N2O) + N2O = (F- • 4N2O)

Quantity Value Units Method Reference Comment
Δr31. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Δr102.J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Fluorine anion • 4Nitrous oxide) + Nitrous oxide = (Fluorine anion • 5Nitrous oxide)

By formula: (F- • 4N2O) + N2O = (F- • 5N2O)

Quantity Value Units Method Reference Comment
Δr26. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Δr107.J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Fluorine anion • 5Nitrous oxide) + Nitrous oxide = (Fluorine anion • 6Nitrous oxide)

By formula: (F- • 5N2O) + N2O = (F- • 6N2O)

Quantity Value Units Method Reference Comment
Δr25. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Δr108.J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Bromine anion • 2Nitrous oxide) + Nitrous oxide = (Bromine anion • 3Nitrous oxide)

By formula: (Br- • 2N2O) + N2O = (Br- • 3N2O)

Quantity Value Units Method Reference Comment
Δr21. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Chlorine anion • Nitrous oxide) + Nitrous oxide = (Chlorine anion • 2Nitrous oxide)

By formula: (Cl- • N2O) + N2O = (Cl- • 2N2O)

Quantity Value Units Method Reference Comment
Δr24. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Δr81.6J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Fluorine anion • Nitrous oxide) + Nitrous oxide = (Fluorine anion • 2Nitrous oxide)

By formula: (F- • N2O) + N2O = (F- • 2N2O)

Quantity Value Units Method Reference Comment
Δr39. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Δr95.0J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Bromine anion • Nitrous oxide) + Nitrous oxide = (Bromine anion • 2Nitrous oxide)

By formula: (Br- • N2O) + N2O = (Br- • 2N2O)

Quantity Value Units Method Reference Comment
Δr23. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Δr91.2J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(H- • 4294967295Nitrous oxide) + Nitrous oxide = H-

By formula: (H- • 4294967295N2O) + N2O = H-

Quantity Value Units Method Reference Comment
Δr248. ± 17.kJ/molTherSheldon, Ohair, et al., 1995gas phase; Acidity between PhCOMe, HCONHMe, near CF3CH2OH. Acid: H2N-NO; B

(Hydronium cation • 2Nitrous oxide) + Nitrous oxide = (Hydronium cation • 3Nitrous oxide)

By formula: (H3O+ • 2N2O) + N2O = (H3O+ • 3N2O)

Quantity Value Units Method Reference Comment
Δr42.7kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Oxygen cation • 2Nitrous oxide) + Nitrous oxide = (Oxygen cation • 3Nitrous oxide)

By formula: (O2+ • 2N2O) + N2O = (O2+ • 3N2O)

Quantity Value Units Method Reference Comment
Δr25.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr79.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Oxygen cation • 3Nitrous oxide) + Nitrous oxide = (Oxygen cation • 4Nitrous oxide)

By formula: (O2+ • 3N2O) + N2O = (O2+ • 4N2O)

Quantity Value Units Method Reference Comment
Δr22.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Oxygen cation • 4Nitrous oxide) + Nitrous oxide = (Oxygen cation • 5Nitrous oxide)

By formula: (O2+ • 4N2O) + N2O = (O2+ • 5N2O)

Quantity Value Units Method Reference Comment
Δr20.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Oxygen cation • 5Nitrous oxide) + Nitrous oxide = (Oxygen cation • 6Nitrous oxide)

By formula: (O2+ • 5N2O) + N2O = (O2+ • 6N2O)

Quantity Value Units Method Reference Comment
Δr18.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Oxygen cation • 6Nitrous oxide) + Nitrous oxide = (Oxygen cation • 7Nitrous oxide)

By formula: (O2+ • 6N2O) + N2O = (O2+ • 7N2O)

Quantity Value Units Method Reference Comment
Δr16.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Hydronium cation • Nitrous oxide) + Nitrous oxide = (Hydronium cation • 2Nitrous oxide)

By formula: (H3O+ • N2O) + N2O = (H3O+ • 2N2O)

Quantity Value Units Method Reference Comment
Δr50.6kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(NO2+ • 3Nitrous oxide) + Nitrous oxide = (NO2+ • 4Nitrous oxide)

By formula: (NO2+ • 3N2O) + N2O = (NO2+ • 4N2O)

Quantity Value Units Method Reference Comment
Δr18.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr88.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(NO2+ • 4Nitrous oxide) + Nitrous oxide = (NO2+ • 5Nitrous oxide)

By formula: (NO2+ • 4N2O) + N2O = (NO2+ • 5N2O)

Quantity Value Units Method Reference Comment
Δr17.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(Oxygen cation • Nitrous oxide) + Nitrous oxide = (Oxygen cation • 2Nitrous oxide)

By formula: (O2+ • N2O) + N2O = (O2+ • 2N2O)

Quantity Value Units Method Reference Comment
Δr31.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(HN2O+ • 2Nitrous oxide) + Nitrous oxide = (HN2O+ • 3Nitrous oxide)

By formula: (HN2O+ • 2N2O) + N2O = (HN2O+ • 3N2O)

Quantity Value Units Method Reference Comment
Δr24.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(HN2O+ • 3Nitrous oxide) + Nitrous oxide = (HN2O+ • 4Nitrous oxide)

By formula: (HN2O+ • 3N2O) + N2O = (HN2O+ • 4N2O)

Quantity Value Units Method Reference Comment
Δr23.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr120.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(HN2O+ • 4Nitrous oxide) + Nitrous oxide = (HN2O+ • 5Nitrous oxide)

By formula: (HN2O+ • 4N2O) + N2O = (HN2O+ • 5N2O)

Quantity Value Units Method Reference Comment
Δr21.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr130.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

(HN2O+ • Nitrous oxide) + Nitrous oxide = (HN2O+ • 2Nitrous oxide)

By formula: (HN2O+ • N2O) + N2O = (HN2O+ • 2N2O)

Quantity Value Units Method Reference Comment
Δr27.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

Chlorine anion + Nitrous oxide = (Chlorine anion • Nitrous oxide)

By formula: Cl- + N2O = (Cl- • N2O)

Quantity Value Units Method Reference Comment
Δr24. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Δr80.3J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

Fluorine anion + Nitrous oxide = (Fluorine anion • Nitrous oxide)

By formula: F- + N2O = (F- • N2O)

Quantity Value Units Method Reference Comment
Δr41. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

Bromine anion + Nitrous oxide = (Bromine anion • Nitrous oxide)

By formula: Br- + N2O = (Br- • N2O)

Quantity Value Units Method Reference Comment
Δr23. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Δr75.7J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

Hydronium cation + Nitrous oxide = (Hydronium cation • Nitrous oxide)

By formula: H3O+ + N2O = (H3O+ • N2O)

Quantity Value Units Method Reference Comment
Δr70.7kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M

C5N2O6W (g) = C5O5W (g) + Nitrous oxide (g)

By formula: C5N2O6W (g) = C5O5W (g) + N2O (g)

Quantity Value Units Method Reference Comment
Δr61.1 ± 2.1kJ/molKinGWeitz, 1994MS
Δr92. ± 8.kJ/molESTBogdan, Wells, et al., 1991MS

C7H8N2O = Nitrous oxide + Norcaradiene

By formula: C7H8N2O = N2O + C7H8

Quantity Value Units Method Reference Comment
Δr-68.5 ± 3.6kJ/molKinOth, Olsen, et al., 1977liquid phase; solvent: THF; At 337K; ALS

2,3-Diazabicyclo[2.2.2]octa-2,5-diene N-oxide = Nitrous oxide + 1,3-Cyclohexadiene

By formula: C6H8N2O = N2O + C6H8

Quantity Value Units Method Reference Comment
Δr-3.5 ± 0.3kJ/molKinOth, Olsen, et al., 1977liquid phase; solvent: THF; At 452 K; ALS

C8H8N2O = Nitrous oxide + Bicyclo[4.2.0]octa-1,3,5-triene

By formula: C8H8N2O = N2O + C8H8

Quantity Value Units Method Reference Comment
Δr-41.2 ± 0.54kJ/molKinOth, Olsen, et al., 1977liquid phase; solvent: THF; At 413 K; ALS

C9H12N2O = Nitrous oxide + Indan, 3a,7a-dihydro-

By formula: C9H12N2O = N2O + C9H12

Quantity Value Units Method Reference Comment
Δr-3.0 ± 0.50kJ/molKinOth, Olsen, et al., 1977liquid phase; solvent: THF; ALS

C8H10N2O = Nitrous oxide + Bicyclo[4.2.0]octa-2,4-diene

By formula: C8H10N2O = N2O + C8H10

Quantity Value Units Method Reference Comment
Δr-9.7 ± 0.4kJ/molKinOth, Olsen, et al., 1977gas phase; At 426 K; ALS

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Aruga, et al., 1993
Hiraoka, K.; Aruga, K.; Fujimaki, S.; Yamabe, S., Comparative Study of the Gas Phase Bond Strengths of CO2 and N2O with the Halide Ions, J. Am. Soc. Mass Spectrom., 1993, 4, 1, 58, https://doi.org/10.1016/1044-0305(93)85043-W . [all data]

Sheldon, Ohair, et al., 1995
Sheldon, J.C.; Ohair, R.A.J.; Downard, K.M.; Gronert, S.; Krempp, M.; Depuy, C.H.; Bowie, J.H., A potential surface map of the H-/N2O system. The gas phase ion chemistry of HN2O-, Aust. J. Chem., 1995, 48, 155. [all data]

Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Sato, T.; Yamabe, S., Gas-Phase Solavtion of NO+, O2+, N2O+, and H3O+ with N2O, J. Chem. Phys., 1994, 101, 5, 4073, https://doi.org/10.1063/1.467524 . [all data]

Weitz, 1994
Weitz, E., J. Phys. Chem., 1994, 98, 11256. [all data]

Bogdan, Wells, et al., 1991
Bogdan, P.L.; Wells, J.R.; Weitz, E., J. Am. Chem. Soc., 1991, 113, 1294. [all data]

Oth, Olsen, et al., 1977
Oth, J.F.M.; Olsen, H.; Synder, J.P., Energetics of heteroextrusion reactions. N2 vs. N2O, J. Am. Chem. Soc., 1977, 99, 8505-8507. [all data]


Notes

Go To: Top, Reaction thermochemistry data, References