Me2C(NO)CH2 anion
- Formula: C4H8NO-
- Molecular weight: 86.1130
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
C4H8NO- + =
By formula: C4H8NO- + H+ = C4H9NO
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1613. ± 26. | kJ/mol | G+TS | Noest and Nibbering, 1980 | gas phase; Between H2O, MeOH |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1586. ± 25. | kJ/mol | IMRB | Noest and Nibbering, 1980 | gas phase; Between H2O, MeOH |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Noest and Nibbering, 1980
Noest, A.J.; Nibbering, N.M.M.,
Homoconjugation vs. charge dipole stabilization interaction effects in the stabilization of carbanions in the gas phase,
J. Am. Chem. Soc., 1980, 102, 6427. [all data]
Notes
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- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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