H2O..ClO2 anion
- Formula: ClH2O3-
- Molecular weight: 85.468
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -411. ± 8.8 | kJ/mol | Ther | Blades, Klassen, et al., 1995 | T: 293 K. ΔSaff approx. 24 cal/mol-K |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Reference | Comment |
|---|---|---|
| 2.810 ± 0.020 | Tschurl and Boesl, 2007 | affinity is difference from ClO2- EA, corrected for calculated neutral BE of 0.09 eV |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P.,
Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I,
J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019
. [all data]
Tschurl and Boesl, 2007
Tschurl, M.; Boesl, U.,
Photodetachment photoelectron spectroscopy of the weakly bound OClO-center dot H2O complex,
Z. Phys. Chem., 2007, 221, 5, 609-618, https://doi.org/10.1524/zpch.2007.221.5.609
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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