ClO4 anion
- Formula: ClO4-
- Molecular weight: 99.451
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Method | Reference | Comment |
|---|---|---|---|
| 5.25 ± 0.10 | LPES | Wang and Wang, 2000 | Vertical Detachment Energy: 5.5±0.1 eV. Acid dHf: see Meyer and Kass, 2010 |
Protonation reactions
ClO4- + = HClO4
By formula: ClO4- + H+ = HClO4
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1255. ± 24. | kJ/mol | IMRB | Meyer and Kass, 2010 | gas phase |
| ΔrH° | 1220. ± 50. | kJ/mol | Acid | Marcus, 1987 | gas phase; Acidity seems too strong by ca. 10 kcal/mol. Other lattice energetics ( Mallouk, Rosenthal, et al., 1984, Finch, Gates, et al., 1977) are also too stable for anions. |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1200. ± 50. | kJ/mol | H-TS | Marcus, 1987 | gas phase; Acidity seems too strong by ca. 10 kcal/mol. Other lattice energetics ( Mallouk, Rosenthal, et al., 1984, Finch, Gates, et al., 1977) are also too stable for anions. |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Wang and Wang, 2000
Wang, X.B.; Wang, L.S.,
The electronic structure and electron affinities of higher chlorine oxide radicals ClOx (x=2-4) from photoelectron spectroscopy of ClOx- anions,
J. Chem. Phys., 2000, 113, 24, 10928-10933, https://doi.org/10.1063/1.1326067
. [all data]
Meyer and Kass, 2010
Meyer, M.M.; Kass, S.R.,
Experimental and Theoretical Gas-Phase Acidities, Bond Dissociation Energies, and Heats of Formation of HClOx, x=1-4,
J. Phys. Chem. A, 2010, 114, 12, 4086-4092, https://doi.org/10.1021/jp100888k
. [all data]
Marcus, 1987
Marcus, Y.,
The Thermodynamics of Solvation of Ions. 2. The Enthalpy of Hydration at 298.15K,
J. Chem. Soc. Farad. Trans. I, 1987, 83, 2, 339, https://doi.org/10.1039/f19878300339
. [all data]
Mallouk, Rosenthal, et al., 1984
Mallouk, T.E.; Rosenthal, G.L.; Muller, G.; Brusasco, R.; Bartlett, N.,
Fluoride ion affinities of GeF4 and BF4 from thermodynamic and structural data for (SF2)2GeF6, ClO2GeF5, and ClO2BF4,
Inorg. Chem., 1984, 23, 3167. [all data]
Finch, Gates, et al., 1977
Finch, A.; Gates, P.N.; Peake, S.J.,
Thermochemistry of polyhalides. III. Cesium and rubidium tetrachloroiodates,
J. Inorg. Nucl. Chem., 1977, 39, 2135. [all data]
Notes
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- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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