dihydrogen telluride


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
176.8 - 271.3.07829599.954-76.2Stull, 1947Coefficents calculated by NIST from author's data.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

HTe- + Hydrogen cation = dihydrogen telluride

By formula: HTe- + H+ = H2Te

Quantity Value Units Method Reference Comment
Δr1385. ± 8.8kJ/molG+TSGal, Maria, et al., 1989gas phase
Δr1386.3 ± 1.7kJ/molD-EAFreidhoff, Snodgrass, et al., 1986gas phase
Δr1393.3kJ/molN/ACheck, Faust, et al., 2001gas phase; ScBr4-.; ; ΔS(EA)=8.4
Quantity Value Units Method Reference Comment
Δr1360. ± 8.4kJ/molIMREGal, Maria, et al., 1989gas phase
Δr1361.2 ± 3.0kJ/molH-TSFreidhoff, Snodgrass, et al., 1986gas phase
Δr1366.9kJ/molN/ACheck, Faust, et al., 2001gas phase; ScBr4-.; ; ΔS(EA)=8.4

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to H2Te+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
Proton affinity (review)735.9kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity704.5kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
9.2 ± 0.1EIBalkis, Gaines, et al., 1976LLK
9.14PEPotts and Price, 1972LLK
9.138 ± 0.005SPrice, Teegan, et al., 1950RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
HTe+11.9 ± 0.2HEIBalkis, Gaines, et al., 1976LLK

De-protonation reactions

HTe- + Hydrogen cation = dihydrogen telluride

By formula: HTe- + H+ = H2Te

Quantity Value Units Method Reference Comment
Δr1385. ± 8.8kJ/molG+TSGal, Maria, et al., 1989gas phase; B
Δr1386.3 ± 1.7kJ/molD-EAFreidhoff, Snodgrass, et al., 1986gas phase; B
Δr1393.3kJ/molN/ACheck, Faust, et al., 2001gas phase; ScBr4-.; ; ΔS(EA)=8.4; B
Quantity Value Units Method Reference Comment
Δr1360. ± 8.4kJ/molIMREGal, Maria, et al., 1989gas phase; B
Δr1361.2 ± 3.0kJ/molH-TSFreidhoff, Snodgrass, et al., 1986gas phase; B
Δr1366.9kJ/molN/ACheck, Faust, et al., 2001gas phase; ScBr4-.; ; ΔS(EA)=8.4; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Gal, Maria, et al., 1989
Gal, J.-F.; Maria, P.-C.; Decouzon, M., The Gas-Phase Acidity and Bond Dissociation Energies of Hydrogen Telluride, Int. J. Mass Spectrom. Ion Proc., 1989, 93, 1, 87, https://doi.org/10.1016/0168-1176(89)83076-9 . [all data]

Freidhoff, Snodgrass, et al., 1986
Freidhoff, C.B.; Snodgrass, J.T.; Coe, J.V.; McHugh, K.M.; Bowen, K.H., Negative ion photoelectron spectroscopy of TeH-, J. Chem. Phys., 1986, 84, 1051. [all data]

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Balkis, Gaines, et al., 1976
Balkis, T.; Gaines, A.F.; Ozgen, G.; Ozgen, I.T.; Flowers, M.C., Ionization of hydrogen sul- phide, selenide and telluride by electron impact, J. Chem. Soc. Faraday Trans. 2, 1976, 72, 524. [all data]

Potts and Price, 1972
Potts, A.W.; Price, W.C., Photoelectron spectra and valence shell orbital structures of groups V VI hydrides, Proc. R. Soc. London A:, 1972, 326, 181. [all data]

Price, Teegan, et al., 1950
Price, W.C.; Teegan, J.P.; Walsh, A.D., The far ultra-violet absorption spectra of the hydrides and deuterides of sulphur, selenium and tellurium and of the methyl derivatives of hydrogen sulphide, Proc. Roy. Soc. (London), 1950, A201, 600. [all data]


Notes

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